28177-54-0

Basic information

• Product Name: Phenol, 2,6-diiodo-
• CAS NO: 28177-54-0
• Molecular Formula: C6H4I2O
• Molecular Weight: 345.906
• Mol File: 28177-54-0.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Phenol, 2,6-diiodo-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,6-diiodo-(28177-54-0)
• EPA Substance Registry System: Phenol, 2,6-diiodo-(28177-54-0)

Safety Data

• Hazardous Substances Data: 28177-54-0(Hazardous Substances Data)

Upstream product

• 49865-78-3 2,6-diiodoaniline 
• 108-95-2 phenol 
• 7553-56-2 iodine 
• 139-02-6 sodium phenoxide 
• 17614-10-7 phenyl N-isopropylcarbamate 
• 99-09-2 3-nitro-aniline 
• 146512-89-2 2,4-diiodo-3-nitroaniline 
• 861606-52-2 1,3-diiodo-2-nitro-benzene 
• 305-85-1 2,6-diiodo-4-nitrophenol 
• 100-02-7 4-nitro-phenol 
• 899427-44-2 2,6-bis(trimethylsilyl)phenyl isopropylcarbamate 
• 899427-47-5 2,6-diiodophenyl isopropylcarbamate 
• 609-23-4 2,4,6-Triiodophenol 
• 2297-82-7 2,6-diiodo-4-aminophenol 

Downstream Products

• 1948-40-9 4-hydroxy-3,5-diiodobenzaldehyde 
• 20389-01-9 2,6-diiodo-p-benzoquinone 
• 38751-61-0 2,6-diiodo-phenetole 
• 305-85-1 2,6-diiodo-4-nitrophenol 
• 13073-26-2 2-iodo-6-nitro-phenol 
• 344324-93-2 1,3-diiodo-2-methoxybenzene 
• 15459-51-5 2,6-di-iodo-4-bromophenol 
• 88-89-1 2,4,6-Trinitrophenol 
• 28818-51-1 (2,6-diiodo-phenoxy)-acetic acid 
• 28165-73-3 2,6-Diiodophenyl acetate 
• 197149-33-0 1,3-diiodo-2-(methoxymethoxy)benzene 
• 609-23-4 2,4,6-Triiodophenol 
• 76469-12-0 3,3',5,5'-tetraiodo-4,4'-diphenol 
• 197149-30-7 2-Iodo-6-methylsulfanyl-phenol 

Relevant articles and documents

Synthesis of Stannylated Aryl Imines and Amines via Aryne Insertion Reactions into Sn?N Bonds

The reaction of in situ generated arynes with stannylated imines to provide ortho-stannyl-aniline derivatives is reported. The readily prepared trimethylstannyl benzophenone imine is introduced as an efficient reagent to realize the aryne σ-insertion reaction. The imine functionality is an established N-protecting group and insertions proceed with good yields and good to excellent regioselectivities. The product anilines are valuable starting materials for follow-up chemistry thanks to the rich chemistry offered by the trimethylstannyl moiety.

Two-stage metal ion sensing by through-space and through-bond charge transfer

A highly selective colorimetric and ratiometric "two-stage"/"off-on"type fluorescent probe with an ability to exclude other heavy and transition metal ions has been designed and synthesized. Low concentrations of Fe3+ cause through-space charge transfer which leads to fluorescence quenching exceeds 96%, and a further increase of Fe3+ concentration results in the formation of a complex with the maximum emission peak of 1,3-bis((E)-2-(pyridin-4-yl)vinyl)-2-methoxy benzene (BPVMB) being shifted largely by 100 nm (from 416 to 516 nm), which was examined by fluorescence, absorption detection and femtosecond transient absorption measurements on the basis of intramolecular charge transfer (ICT).

Synthesis of Silylbiaryl Triflates by Chemoselective Suzuki Reaction

A modular approach for the synthesis of functionalized silylbiaryl triflates has been developed. Iodinated silylaryl triflates were prepared via a gram-scale diiodination reaction, followed by a one-flask transformation, in 42-52% overall yield. The iodin