28213-80-1Relevant articles and documents
Photoredox Catalyzed Sulfonylation of Multisubstituted Allenes with Ru(bpy)3Cl2 or Rhodamine B
Chen, Jingyun,Chen, Shufang,Jiang, Jun,Lu, Qianqian,Shi, Liyang,Xu, Zekun,Yimei, Zhao
supporting information, (2021/11/09)
A highly regio- and stereoselective sulfonylation of allenes was developed that provided direct access to α, β-substituted unsaturated sulfone. By means of visible-light photoredox catalysis, the free radicals produced by p-toluenesulfonic acid reacted with multisubstituted allenes to obtain Markovnikov-type vinyl sulfones with Ru(bpy)3Cl2 or Rhodamine B as photocatalyst. The yield of this reaction could reach up to 91%. A series of unsaturated sulfones would be used for further transformation to some valuable compounds.
Method for preparing 1-cyclopropylnaphthalene
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Paragraph 0044-0046; 0050-0051; 0056-0058; 0061; 0064; ..., (2021/07/09)
The invention belongs to the technical field of organic synthesis, and particularly discloses a method for preparing 1-cyclopropylnaphthalene. According to the method disclosed by the invention, 1-naphthylacetophenone is adopted as a raw material, and 1-cyclopropylnaphthalene can be simply and conveniently synthesized through reduction, dehydration, cyclization and reductive dehalogenation. The method has the advantages of cheap and easily available raw materials, no need of precious metals or dangerous organic metal reagents, low raw material cost, convenient production, environmental protection and safety, and is very suitable for industrial production. The method disclosed by the invention has the advantages of high yield in each step, few byproducts and easiness in purification.
Oxidative Alkenylation of Arenes Using Supported Rh Materials: Evidence that Active Catalysts are Formed by Rh Leaching
Luo, Zhongwen,Whitcomb, Colby A.,Kaylor, Nicholas,Zhang, Yulu,Zhang, Sen,Davis, Robert J.,Gunnoe, T. Brent
, p. 260 - 270 (2020/12/01)
This work focuses on the synthesis of supported Rh materials and study of their efficacy as pre-catalysts for the oxidative alkenylation of arenes. Rhodium particles supported on silica (Rh/SiO2; ~3.6 wt% Rh) and on nitrogen-doped carbon (Rh/NC