28282-35-1Relevant articles and documents
Investigations into the Mechanism of Inter- And Intramolecular Iron-Catalyzed [2 + 2] Cycloaddition of Alkenes
Chirik, Paul J.,Hoyt, Jordan M.,Joannou, Matthew V.
supporting information, p. 5314 - 5330 (2020/04/10)
Mechanistic studies are reported on the inter- and intramolecular [2 + 2] alkene cycloadditions to form cyclobutanes promoted by (tricPDI)Fe(N2) (tricPDI = 2,6-(2,4,6-tricyclopentyl)C6H2N = CMe)2
Deazetation of a Bicyclic Azo Compound: Resolution of a Stereochemical Ambiguity and Conformational Analysis of a Biradical
Samuel, Christopher J.
, p. 1259 - 1265 (2007/10/02)
Development of a new approach has permitted a fuller analysis of the stereochemistry of deazetation of the stereospecifically deuteriated azo compound (1d) than could be achieved previously, in that it has proved possible to analyse 2H2>octa-1,7-diene for E,E-, E,Z,-and Z,Z-content.This has given results for the thermal and photochemical reactions that can be rationalised in terms of partial conformational equilibration of the biradical.
Unusual Stereochemistry in the Thermal Deazetation of a Bicyclic Azo Compound
Samuel, Christopher J.
, p. 131 - 132 (2007/10/02)
Thermolysis of the stereospecifically deuteriated azo-compound (1D) led to bicyclo-octane (3) with complete retention and octadiene (4) with partial loss of stereochemistry.