286967-31-5Relevant academic research and scientific papers
Non-chelation controlled 1,3-asymmetric induction in β-chiral acylsilanes
Nakada, Masahisa,Urano, Yasuharu,Kobayashi, Susumu,Ohno, Masaji
, p. 741 - 744 (1994)
The diastereoselectivity of nucleophilic adition to β-chiral acylsilanes is examined, and our method is applied to the stereoselective synthesis of calcitriol lactone, a major metabolite of vitamin D3.
