Non-chelation controlled 1,3-asymmetric induction in β-chiral acylsilanes

DOI: 10.1016/S0040-4039(00)75805-9

Source and publish data:

Tetrahedron Letters p. 741 - 744 (1994)

Update date:2022-08-05

Topics:

Authors:

Nakada, Masahisa

Urano, Yasuharu

Kobayashi, Susumu

Ohno, Masaji

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Article abstract of DOI:10.1016/S0040-4039(00)75805-9

The diastereoselectivity of nucleophilic adition to β-chiral acylsilanes is examined, and our method is applied to the stereoselective synthesis of calcitriol lactone, a major metabolite of vitamin D₃.

Full text of DOI:10.1016/S0040-4039(00)75805-9

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