287-25-2

Basic information

• Product Name: 2H-Oxete
• Synonyms: 2H-Oxete;Oxeten;oxetene
• CAS NO: 287-25-2
• Molecular Formula: C₃H₄O
• Molecular Weight: 0
• Mol File: 287-25-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-Oxete(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Oxete(287-25-2)
• EPA Substance Registry System: 2H-Oxete(287-25-2)

Safety Data

• Hazardous Substances Data: 287-25-2(Hazardous Substances Data)

Upstream product

• 75700-25-3 3-oxetanyl o-nitrophenyl selenide 
• 74898-48-9 C₁₀H₁₁N₂O₃S^(1-)*Li⁽¹⁺⁾ 
• 107-02-8 acrolein 
• 187737-37-7 propene 

Downstream Products

• 108-32-7 1,2-propylene cyclic carbonate 
• 1261061-75-9 N-{[1-(2-hydroxypropyl)-pyrrolidine-(3R)-yl-carbamoyl]-methyl}-3-trifluoromethylbenzamide 
• 3068-88-0 4-methyloxetan-2-one 
• 67-64-1 acetone 
• 107-02-8 acrolein 
• 503-30-0 trimethylene oxide 

Relevant articles and documents

A CLASSIFICATION OF THE PHOTOCHEMICAL ELECTROCYCLIC REACTIONS OF HETEROATOM CONJUGATED SYSTEMS

Photochemical electrocyclic reaction mechanism of a variety of heteroatom conjugated systems has been elucidated by a unique concept.The proposed classification of the reaction, which is based upon the number and types of electrons involved in the reaction centers, takes into account the participation of the lone-pair electrons and gives the correct description of the electron behavior during the electrocyclic reaction process.

Gas-phase epoxidation of propylene over iron-containing catalysts: The effect of iron incorporation in the support matrix

The gas-phase epoxidation of propylene using iron as a catalytically active metal has been studied. The XRD-amorphous silica nanopowder was found to host active as well as redox-silent iron species, using nitrous oxide as an oxidizing agent. The presence of iron oxide nanoparticles was proven in the most active catalysts, indicating that the epoxidation proceeds over nanoparticles rather than over isolated iron atoms. A combination of XPS, TEM and voltammetric techniques elucidated the mechanism of the formation of catalytically active forms of iron oxide, distinguishing selective forms from unselective and inactive ones in the epoxidation reaction. Transition response experiments showed a good correlation between epoxidation activity, N2O decomposition and electrochemical specification of iron oxides.

Oxetene: Synthesis and Energetics of Electrocyclic Ring Opening

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