290820-91-6Relevant academic research and scientific papers
One-step synthesis of size tuned zinc selenide quantum dots via a temperature controlled molecular precursor approach
Jun, Young-Wook,Koo, Ja-Eung,Cheon, Jinwoo
, p. 1243 - 1244 (2000)
One-step size-controlled synthesis of ZnSe quantum dots is studied and the obtained QDs are luminescent with the emission wavelength varying over a wide range (up to 100 nm) depending on the particle size; the single- molecular precursor is an air-stable
Coordination complexes of zinc with reactive ESiMe3 (E = S, Se, Te) ligands
DeGroot, Marty W.,Corrigan, John F.
, p. 3378 - 3385 (2008/10/09)
The complexes (N,N′-tmeda)Zn(ESiMe3)2 (E = S, 1a; E = Se, 2a; E = Te, 3a) and (3,5-Me2-C5H 3N)2Zn(ESiMe3)2 (E = S, 1b; E = Se, 2b; E = Te, 3b) have been prepared in high yield by the reaction of E(SiMe 3)2 with (N,N′-tmeda)Zn(OAc)2 (4a) and (3,5-Me2-C5H3N)2-Zn(OAc) 2 (4b), respectively. Complexes 1-3 have been characterized spectroscopically and by means of single-crystal X-ray diffraction. All six complexes exist in the solid state as monomeric species with terminally bonded trimethylsilylchalcogenolate moieties and a distorted tetrahedral geometry of the zinc center.
