96313-35-8Relevant academic research and scientific papers
Reaction of Acyl Chlorides with in Situ Formed Zinc Selenolates: Synthesis of Selenoesters versus Ring-Opening Reaction of Tetrahydrofuran
Bellino, Gemma,Scisciani, Marialaura,Vargas, Jaqueline Pinto,Sancineto, Luca,Bagnoli, Luana,Marini, Francesca,Lüdtke, Diogo Seibert,Lenardao, Eder Joao,Santi, Claudio
, (2016)
Attempting to apply the in situ production of PhSeZnSePh to the synthesis of selenoesters, an unexpected reaction involving the solvent (tetrahydrofuran) was observed and studied. We reported here some evidences about the mechanism and the possibility to
Atom efficient preparation of zinc selenates for the synthesis of selenol esters under “On Water” conditions
Sancineto, Luca,Vargas, Jaqueline Pinto,Monti, Bonifacio,Arca, Massimiliano,Lippolis, Vito,Perin, Gelson,Lenardao, Eder Joao,Santi, Claudio
, (2017/06/29)
We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)2Zn] or [(PhSe)2Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.
On water preparation of phenylselenoesters
Santi, Claudio,Battistelli, Benedetta,Testaferri, Lorenzo,Tiecco, Marcello
supporting information; experimental part, p. 1277 - 1280 (2012/06/04)
PhSeZn-halides react under "on water" mild conditions with acid chlorides to provide a high yield route to a variety of aromatic and aliphatic phenylselenoesters.
Water accelerated Sm/TMSC1 reductive cleavage of the Se-Se bond: Synthesis of selenoesters and selenoformates
Wang, Lei,Zhang, Yongmin
, p. 3107 - 3115 (2007/10/03)
The reduction of diselenides by the Sm/TMSC1/H2O system led to selenide anions. These 'living' species reacted smoothly with acid chlorides, acid anhydrides and methyl chloroformate respectively to afford the desired selenoesters and selenoform
