2972-65-8

Usage

Uses

Used in Agriculture:
2,4-Diphenoxy-6-chloro-1,3,5-triazine is used as a selective herbicide for controlling broadleaf weeds in various crops such as cereals, sugar beet, and maize. It is applied to protect these crops from weed competition, ensuring healthier growth and higher yields.
Used in Environmental Management:
2,4-Diphenoxy-6-chloro-1,3,5-triazine is used as a tool in environmental management to minimize the impact of broadleaf weeds on ecosystems. However, due to its persistence and potential to leach into groundwater, its application is carefully regulated to balance agricultural productivity with environmental protection and human health considerations.

InChI:InChI=1/C15H10ClN3O2/c16-13-17-14(20-11-7-3-1-4-8-11)19-15(18-13)21-12-9-5-2-6-10-12/h1-10H

Upstream product

• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 108-95-2 phenol 
• 30886-26-1 2,4-dichloro-6-(4-chlorophenoxy)-1,3,5-triazine 
• 106-48-9 4-chloro-phenol 
• 4682-78-4 2,4-dichloro-6-phenoxy-1,3,5-triazine 

Downstream Products

• 132353-26-5 Benzoic acid 4,6-diphenoxy-[1,3,5]triazin-2-yl ester 
• 83773-73-3 2-[4-(4,6-Diphenoxy-[1,3,5]triazin-2-yl)-piperazin-1-yl]-6,7-dimethoxy-quinazolin-4-ylamine 
• 4036-50-4 2-piperidyl-4,6-diphenoxy-1,3,5-triazine 
• 1221744-11-1 2-(carbazol-9'-yl)-4,6-bisphenoxy-1,3,5-triazine 
• 1436522-42-7 2-(N,N-bis(2-pyridyl)amino)-4,6-bis(phenoxy)-1,3,5-triazine 
• 1514792-45-0 9-[4-(4,6-diphenoxy-1,3,5-triazin-2-yl)phenyl]-9H-carbazole 

Relevant academic research and scientific papers

Novel blue fluorophor with high triplet energy level for high performance single-emitting-layer fluorescence and phosphorescence hybrid white organic light-emitting diodes

On the basis of a D-π-A structural strategy incorporating diphenylamine as an electron-donor and 1,3,5-triazine as an electron-acceptor with a short benzene π-conjugated feature, 4-(4,6-diphenoxy-1,3,5-triazin-2-yl)-N,N- diphenylaniline (POTA), a novel bl

Investigating Triorthogonal Chemoselectivity. Effect of Azide Substitution on the Triazine Core

An example of triorthogonal chemoselectivity is reported here for the first time. In this regard, a series of 43 reactions were performed using tridentate s-triazine as a model. In all of the possible cases, the three substitutions were carried out using

Comparative study of multi-functional luminogens with 1,3,5-triazine as the core and phenothiazine or phenoxy donors as the peripheral moieties for non-doped/doped fluorescent and red phosphorescent OLEDs

A series of three-armed fluorescent emitters based on a 1,3,5-triazine acceptor as the central core and phenothiazine or phenoxy moieties as the different peripheral units, are designed and synthesized. All of them exhibit aggregation-induced emission enhancement and thermally activated delayed fluorescence. Photoluminescence quantum yields exceeded 37 and 67% for non-doped and doped solid-state samples respectively. The compounds were found to be capable of transporting both holes and electrons. The highest mobility values of more than 1 × 10?4 cm2V?1s?1 were obtained for the compound having three phenothiazine moieties at electric field of more than 1 × 106 Vcm?1. Additionally, three types of organic light emitting diodes based on these materials were fabricated. The device containing non-doped emission layer with the compound containing single phenothiazine moiety as the emitter gave maximum external quantum efficiency of 5.4%. The device with doped emission layer containing 5% solid solution of the compound having three phenothiazine moieties in an appropriate host gave maximum external quantum efficiency of 9.9%. The phosphorescent device hosted by the compound with single phenothiazine unit exhibited maximum external quantum efficiency of 10.3% and a low-efficiency roll-offs of 1% at 1000 cd/m2.

Metal-Assisted and Solvent-Mediated Synthesis of Two-Dimensional Triazine Structures on Gram Scale

Covalent triazine frameworks are an emerging material class that have shown promising performance for a range of applications. In this work, we report on a metal-assisted and solvent-mediated reaction between calcium carbide and cyanuric chloride, as cheap and commercially available precursors, to synthesize two-dimensional triazine structures (2DTSs). The reaction between the solvent, dimethylformamide, and cyanuric chloride was promoted by calcium carbide and resulted in dimethylamino-s-triazine intermediates, which in turn undergo nucleophilic substitutions. This reaction was directed into two dimensions by calcium ions derived from calcium carbide and induced the formation of 2DTSs. The role of calcium ions to direct the two-dimensionality of the final structure was simulated using DFT and further proven by synthesizing molecular intermediates. The water content of the reaction medium was found to be a crucial factor that affected the structure of the products dramatically. While 2DTSs were obtained under anhydrous conditions, a mixture of graphitic material/2DTSs or only graphitic material (GM) was obtained in aqueous solutions. Due to the straightforward and gram-scale synthesis of 2DTSs, as well as their photothermal and photodynamic properties, they are promising materials for a wide range of future applications, including bacteria and virus incapacitation.

Choline Hydroxide as a Versatile Medium for Catalyst-Free O-Functionalization of Phenols

A versatile synthetic protocol for benzyl phenyl ether preparation via O-alkylation of phenolic oxygen with readily available benzyl derivatives was demonstrated. The newly designed procedure was carried out using an eco-friendly medium, room-temperature ionic liquid (choline hydroxide), under metal- and base-catalyst-free aerobic conditions. The reaction platform was also successfully applied to phenol protection strategy.

Aromatic compound and organoelectroluminescent device comprising the compound

The present invention relates to a novel aromatic compound and an organic electroluminescent device comprising the same. The present invention relates to an organic electroluminescent device including an aromatic compound. (by machine translation)

Design, Synthesis and Biological Evaluation of Novel Nonsteroidal Progesterone Receptor Antagonists Based on Phenylamino-1,3,5-triazine Scaffold

We report here the development of phenylamino-1,3,5-triazine derivatives as novel nonsteroidal progesterone receptor (PR) antagonists. PR plays key roles in various physiological systems, including the female reproductive system, and PR antagonists are promising candidates for clinical treatment of multiple diseases. By using the phenylamino-1,3,5-triazine scaffold as a template structure, we designed and synthesized a series of 4-cyanophenylamino-1,3,5-triazine derivatives. The synthesized compounds exhibited PR antagonistic activity, and among them, compound 12n was the most potent (IC50=0.30μM); it also showed significant binding affinity to the PR ligand-binding domain. Docking simulation supported the design rationale of the compounds. Our results suggest that the phenylamino-1,3,5-triazine scaffold is a versatile template for development of nonsteroidal PR antagonists and that the developed compounds are promising lead compounds for further structural development of nonsteroidal PR antagonists.

One-pot synthesis of triazines as potential agents affecting cell differentiation

Abstract: This paper outlines the synthesis of a number of structural analogs of 3-[(4,6-diphenoxy-1,3,5-triazin-2-yl)amino]benzoic acid which represent compounds with potential cardiogenetic activity. A one-pot protocol was developed for swift functionalization of the 1,3,5-triazine core without the need of isolating intermediates. The developed route starts from readily available 2,4,6-trichloro-1,3,5-triazine, displacing the chlorine atoms sequentially by aryloxy, arylamino, or arylthio moieties to enable access to molecules with three different substituents of this type in good yields. To facilitate purification, tert-butyl, methyl, and ethyl ester derivatives of the target compounds were initially synthesized. The tert-butyl esters could be readily hydrolyzed to the desired compounds, while reduction of the methyl and ethyl esters gave the corresponding benzylic alcohols in high yields, thereby expanding the substrate scope for future relevant cell assays. Graphical abstract: [Figure not available: see fulltext.].

Electronic device including phosphine oxide functionalized triazine derivative and novel phosphine oxide functionalized triazine derivative

Provided are an electronic device including a novel structured interface material capable of improving interface properties of the electronic device, and the novel interface material, and more specifically, an electronic device including the interface mat

Highly Active Manganese-Mediated Acylation of Alcohols with Acid Chlorides or Anhydrides

To explore further the practical uses of highly active manganese (Mn?), a variety of alcohols were treated with Mn?, and the resulting complexes were coupled with acid chlorides and/or acetic anhydride in the absence of any extra catalyst. The subsequent reactions took place smoothly under mild conditions, providing the corresponding O-acylation products in good to excellent isolated yields.