3002-33-3

Basic information

• Product Name: Benzene, 1-nitro-3-[(4-nitrophenyl)methyl]-
• CAS NO: 3002-33-3
• Molecular Formula: C13H10N2O4
• Molecular Weight: 258.233
• Mol File: 3002-33-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-3-[(4-nitrophenyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-3-[(4-nitrophenyl)methyl]-(3002-33-3)
• EPA Substance Registry System: Benzene, 1-nitro-3-[(4-nitrophenyl)methyl]-(3002-33-3)

Safety Data

• Hazardous Substances Data: 3002-33-3(Hazardous Substances Data)

Upstream product

• 5840-41-5 1-benzyl-3-nitrobenzene 
• 872275-05-3 2-nitro-4-(4-nitro-benzyl)-aniline 
• 157195-20-5 (3-nitro-phenyl)-(4-nitro-phenyl)-acetic acid 
• 619-73-8 4-nitrobenzyl chloride 
• 7664-93-9 sulfuric acid 
• 98-95-3 nitrobenzene 
• 13331-27-6 m-nitrobenzene boronic acid 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 76472-81-6 N-[4-(phenylmethyl)phenyl]acetamide 
• 500350-36-7 acetic acid-(4-benzyl-2-nitro-anilide) 
• 876496-87-6 acetic acid-[2-nitro-4-(4-nitro-benzyl)-anilide] 
• 117-34-0 2,2-diphenylacetic acid 
• 2971-22-4 2,2-bis(phenyl)-1,1,1-trichloroethane 
• 619-25-0 3-Nitrobenzyl alcohol 

Downstream Products

• 611-81-4 (3-hydroxyphenyl)(4-hydroxyphenyl)methanone 
• 51458-66-3 3,4'-diamino benzophenone 
• 1469-74-5 3,4'-dinitrobenzophenone 
• 19430-83-2 3,4'-diaminodiphenylmethane 

Relevant articles and documents

Transition Metal Free Nucleophilic Benzylation of Nitroarenes. Umpolung of the Friedel Crafts Reaction

Benzyl chloride and its derivatives are efficiently deprotonated with strong bases to form α-chlorocarbanions. These anions are long-lived enough to enter VNS reactions with nitroarenes or nitroheteroarenes to give a variety of unsymmetrical o- and p-nitrodiarylmethanes. Selectivity of the reaction can be controlled to some extent by changing metal counterions of the base. (Figure presented.).