30078-65-0Relevant articles and documents
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Doddi et al.
, p. 4303,4304, 4305 (1978)
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An Efficient Synthesis of Nitriles from Aldoximes in the Presence of Trifluoromethanesulfonic Anhydride in Mild Conditions
Uludag, N.
, p. 1640 - 1645 (2020/10/22)
Abstract: A new and convenient protocol has been proposed for the transformation of aldoximes to nitriles using trifluoromethanesulfonic anhydride and triethylamine. The proposed method allows a range of aldoximes, including aromatic, heterocyclic, aliphatic, and cycloaliphatic aldoximes, to be converted to the corresponding nitriles in good to excellent yields.
O-BENZENESULFONYL-ACETOHYDROXAMIC ACID ESTER DERIVATIVE AND MANUFACTURING METHOD OF NITRYL COMPOUND
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Paragraph 0033; 0035-0037, (2017/10/26)
PROBLEM TO BE SOLVED: To provide a novel synthetic agent for manufacturing a nitryl compound without using a hydroxylamine derivative which has problems in storage property or handleability. SOLUTION: There is related O-benzene sulfonyl-acetohydroxamic acid ester derivative represented by the following chemical formula, where R1 is H, CF3 or CH3, R2 is CH3, C2H5 or C3H7. There is related a nitryl compound synthesizing agent for synthesizing a nitryl compound from an aldehyde compound containing the O-benzene sulfonyl-acetohydroxamic acid ester derivative and further a manufacturing method of a nitryl compound including a process for transferring the aldehyde compound to oxime in the presence of the synthesizing agent, an organic solvent and an acid catalyst. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT
