30457-88-6

Basic information

• Product Name: 2-BENZYL-PROPENAL
• Synonyms: 2-BENZYL-PROPENAL;2-benzylacrylaldehyde
• CAS NO: 30457-88-6
• Molecular Formula: C₁₀H₁₀O
• Molecular Weight: 146.1858
• Mol File: 30457-88-6.mol
• Article Data: 48

Chemical Properties

• Boiling Point: 110-112 °C(Press: 8.03 Torr)
• Appearance: /
• Density: 0.991±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-BENZYL-PROPENAL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BENZYL-PROPENAL(30457-88-6)
• EPA Substance Registry System: 2-BENZYL-PROPENAL(30457-88-6)

Safety Data

• Hazardous Substances Data: 30457-88-6(Hazardous Substances Data)

Upstream product

• 7795-99-5 1-ethoxy-2-ethoxymethyl-3-phenyl-propan-2-ol 
• 110-88-3 1,3,5-Trioxan 
• 100-42-5 styrene 
• 660-68-4 diethyl amine hydrochloride 
• 108-18-9 diisopropylamine 
• 50-00-0 formaldehyd 
• 104-53-0 3-phenyl-propionaldehyde 
• 75-09-2 dichloromethane 
• 768-56-9 4-Phenylbut-1-ene 
• 109-89-7 diethylamine 
• 75-11-6 diiodomethane 
• 103-67-3 benzyl-methyl-amine 
• 74-95-3 1,1-dibromomethane 
• 51075-22-0 1-(trimethyl-silyloxy)-3-phenyl-1-propene 

Downstream Products

• 1228504-58-2 2-(1-iodo-3-phenylpropan-2-yl)-1,3-dioxolane 
• 1266373-37-8 benzyl (S)-2-benzyl-2-formylaziridine-1-carboxylate 
• 1266373-38-9 tert-butyl (S)-2-benzyl-2-formylaziridine-1-carboxylate 
• 1224850-48-9 (2R)-2,3-epoxy-2-benzylpropanol 
• 1353899-80-5 3-(4-fluorobenzyl)-5-benzyltetrahydro-3-nitro-2H-pyran 
• 1353899-75-8 C₁₃H₁₇NO₄ 

Relevant articles and documents

Rh(III)-Catalyzed Csp2?Csp3 Bond Cleavage/Carbonylethylation of α-Indolyl Alcohols

A Rh(III)-catalyzed Csp2?Csp3 bond cleavage/carbonylethylation of α-indolyl alcohols with allylic alcohols has been reported. This transformation involved a cascade C?C bond cleavage/C?C bond formation, and provides a novel approach to assemble 2-carbonylethylindole skeletons. (Figure presented.).

Rhodium-Catalyzed Regio- And Enantioselective Allylic Amination of Racemic 1,2-Disubstituted Allylic Phosphates

Alkynylphosphines are rarely used as ligands in asymmetric metal catalysis. We synthesized a series of chiral bis(oxazoline)alkynylphosphine ligands and used them in Rh-catalyzed highly regio- and enantioselective allylic amination reactions of 1,2-disubstituted allylic phosphates. Chiral 1,2-disubstituted allylic amines were synthesized in up to 95% yield with >20:1 branched/linear (b/l) ratio and 99% ee from racemic 1,2-disubstituted allylic precursors. The sterically smaller linear alkynyl group on the P atom in the bis(oxazoline)alkynylphosphine ligands was the key to fit the new requirements of the introduction of bulky 2-R′ groups.

Enantioselective hydroesterificative cyclization of 1,6-enynes to chiral γ-lactams bearing a quaternary carbon stereocenter

A palladium-catalyzed asymmetric hydroesterification-cyclization of 1,6-enynes with CO and alcohol was developed to efficiently prepare a variety of enantioenriched γ-lactams bearing a chiral quaternary carbon center and a carboxylic ester group. The approach featured good to high chemo-, region-, and enantioselectivities, high atom economy, and mild reaction conditions as well as broad substrate scope. The correlation between the multiple selectivities of such process and the N-substitutes of the amide linker in the 1,6-enyne substrate has been depicted by the crystallographic evidence and control experiments.