30765-95-8Relevant articles and documents
Electrochemical-mediated fixation of CO2: three-component synthesis of carbamate compounds from CO2, amines andN-alkenylsulfonamides
Liang, Ying,Pan, Ying-Ming,Tang, Hai-Tao,Xiong, Ting-Kai,Zhang, Min,Zhou, Xue-Qi
supporting information, p. 4328 - 4332 (2021/06/30)
An electrocatalyzed three-component cascade reaction of CO2, amines, andN-alkenylsulfonamides is developed, providing an environmentally friendly and efficient method of synthesizing a series of new carbamate compounds. This reaction meets the needs of green chemistry and promotes the participation of carbon dioxide in the three-component reaction by electro-oxidation. Pharmacological activity studies further prove that carbamate compounds have better activity than diamination by-products.
Directing-group-assisted markovnikov-selective hydrothiolation of styrenes with thiols by photoredox/cobalt catalysis
Xiao, Qian,Zhang, Hong,Li, Jing-Hong,Jian, Jing-Xin,Tong, Qing-Xiao,Zhong, Jian-Ji
supporting information, p. 3604 - 3609 (2021/05/10)
In contrast with the well-developed radical thiol-ene reaction to access anti-Markovnikov-type products, the research on the catalytic Markovnikov-selective hydrothiolation of alkenes is very restricted. Because of the catalyst poisoning of metal catalysts by organosulfur compounds, limited examples of transition-metal-catalyzed thiol-ene reactions have been reported. However, in this work, a directing-group-assisted hydrothiolation of styrenes with thiols by photoredox/cobalt catalysis is found to proceed smoothly to afford Markovnikov-type sulfides with excellent regioselectivity.
Ruthenium Amide Complexes – Synthesis and Catalytic Activity in Olefin Metathesis and in Ring-Opening Polymerisation
Gawin, Anna,Pump, Eva,Slugovc, Christian,Kajetanowicz, Anna,Grela, Karol
supporting information, p. 1766 - 1774 (2018/05/14)
A set of olefin metathesis catalysts bearing a ruthenium amide moiety was synthesised. In the ruthenium amide form these complexes exhibit very low activity in standard metathesis reactions. However, a dramatic increase of activity was observed upon in si