3118-85-2

Usage

Purification Methods

Crystallise D-gluconamide from EtOH or 1,2-dimethoxyethane. It mutarotates slowly and hydrolytically in aqueous solution from +30.7o to +13.8o in 80hours to give ammonium D-gluconate which recrystallises from 95% EtOH with m 153-154o and [] D +11.8o (c 3, H2O). [Wolfrom et al. J Am Chem Soc 80 944 1958, Beilstein 3 VI 1259.]

InChI:InChI=1/C6H13NO6/c7-6(13)5(12)4(11)3(10)2(9)1-8/h2-5,8-12H,1H2,(H2,7,13)/t2-,3-,4+,5-/m1/s1

Upstream product

• 74421-63-9 ethyl D-mannonate 
• 101540-37-8 2,3,4,5,6-penta-O-acetyl-D-gluconamide 
• 109-95-5 ethyl nitrite 
• 69489-87-8 D-gluconic acid hydrazide 
• 64-19-7 acetic acid 
• 90-80-2 D-Glucono-1,5-lactone 
• 1198-69-2 D-glucono-1,4-lactone 
• 50-99-7 D-glucose 
• 67008-28-0 L-mannonic acid amide 
• 22430-23-5 L-mannono-1,4-lactone 
• 7256-14-6 D-galactonamide 
• 14965-96-9 L-galactonic acid amide 

Downstream Products

• 526-95-4 gluconic acid 
• 10323-20-3 D-Arabinose 
• 29505-20-2 2,3,4,5,6-penta-O-benzoyl-D-glucononitrile 
• 29556-77-2 penta-O-benzoyl-D-gluconic acid amide 
• 29556-78-3 N-Benzoyl-penta-O-benzoyl-D-gluconamid 

Relevant academic research and scientific papers

Glucose-specific poly(allylamine) hydrogels-A reassessment

Polymer hydrogels synthesized by crosslinking poly(allylamine hydrochloride) with (±)-epichlorohydrin in the presence of d-glucose-6-phosphate monobarium salt do not show imprinting on the molecular level. A series of hydrogels was prepared using the following five templates: d-glucose-6-phosphate monobarium salt, d-glucose, l-glucose, barium hydrogen phosphate (BaHPO4), and d-gluconamide; a hydrogel was also prepared in the absence of a template. For all six hydrogels, batch binding studies were conducted with d-glucose, l-glucose, d-fructose, and d-gluconamide. The extent of analyte sugar binding was determined using 1H NMR. Each hydrogel shows approximately the same relative binding affinity for the different sugar derivatives, and none displays selectivity for either glucose enantiomer. The results of the binding studies correlate with the octanol-water partition coefficients of the sugars, indicative that differential solubilities in the bulk polymer account for the binding affinities observed. Thus, in contrast to templated hydrogels prepared using methacrylate- or acrylamide-based reagents, true imprinting does not occur in this novel, crosslinked-poly(allylamine hydrochloride) system.

Direct oxidative amidation of aldoses by iodine in ammonia water

Aldopentoses, aldohexoses and the benzylated derivatives reacted with iodine in ammonia water at room temperature to give their corresponding saccharide amides in high yields. The reactions proceeded with oxidation of the aldose hemiacetals by iodine to g

Oral hygiene compositions comprising heteroatom containing alkyl aldonamide compounds

The present invention is related to new oral hygiene compositions that have improved foam, viscosity, clarity and good taste due to the inclusion of a new type of alkyl aldonamide compound, specifically heteroatom containing alkyl aldonamide compounds.

Hair care compositions comprising heteroatom containing alkyl aldonamide compounds

The invention relates to hair care compositions containing heteroatom containing alkyl aldonamide compounds and hair conditioning agents. Unexpectedly, applicants have found that when these heteroatom containing alkyl aldonamides are used, benefits such as enhanced stability and/or enhanced viscosity are obtained relative to the use of other known thickeners or non-heteroatom containing aldonamides.

Personal product compositions comprising heteroatom containing alkyl aldonamide compounds

The invention relates to personal product compositions containing heteroatom containing alkyl aldonamide compounds and skin conditioning agent. Unexpectedly, applicants have found that when these heteroatom containing alkyl aldonamides are used, benefits such as enhanced stability and/or enhanced viscosity are obtained relative to the use of other known thickeners or non-heteroatom containing aldonamides.

Sulfated polyhydroxy compounds as anionic surfactants and a process for their manufacture

The present invention relates to sulfated polyhydroxy compounds used as anionic surfactants and to processes for their manufacture.

Heteroatom containing alkyl aldonamide compounds as superior foaming, more soluble nonionic surfactants and a process for their manufacture

The present invention relates to a process for producing amido heteroatom containing alkyl aldonamides comprising reacting an amino heteroatom containing alkyl aldonamide and an acid anhydride in water or solvent; heating the mixture and recovering. A second embodiment of the invention relates to a process for making alkoxylated derivatives of heteroatom containing alkyl aldonamide compounds.