313344-25-1

Upstream product

• 5544-60-5 4-(benzyloxy)benzyl bromide 
• 108-98-5 thiophenol 
• 620176-93-4 methyl (2S)-N-phenylmethylene-2-amino-3-(4-benzyloxyphenyl)propionate 
• 934744-85-1 C₂₄H₂₂O₆ 
• 75691-28-0 methyl (S)-2-(benzylideneamino)-4-methylpentanoate 
• 7517-19-3 methyl (L)-leucinate hydrochloride 
• 100-52-7 benzaldehyde 
• 13803-83-3 methyl (S)-2-(benzylideneamino)-3-methylbutanoate 
• 66646-88-6 methyl 2-(benzylideneamino)acetate 
• 53933-42-9 2-(benzylidene-amino)-propionic acid methyl ester 
• 67628-17-5 (S)-{[1-(4-Methoxy-phenyl)-meth-(E)-ylidene]-amino}-phenyl-acetic acid methyl ester 
• 100-39-0 benzyl bromide 
• 120-47-8 Ethyl 4-hydroxybenzoate 
• 395649-41-9 methyl (E)-2-(benzylideneamino)propanoate 

Downstream Products

• 66123-90-8 4-(fur-2-ylmethyl)phenol 

Relevant academic research and scientific papers

Solid phase Diels-Alder/retro Diels-Alder reactions. A new method for traceless linker strategy

A resin-bound furan has been efficiently synthesized from Merrifield resin. This new polymer reacts with an acetylenic dienophile to afford a thermally stable Diels-Alder adduct. Transformation of the adduct by Michael reaction with thiophenol has allowed an easy retro Diels-Alder reaction. This 'safety-catch' procedure leads to the formation of a chemically and stereochemically pure alkene and to the regeneration of the polymer-bound furan. (C) 2000 Elsevier Science Ltd.

Short and efficient synthesis of 2H-pyrroles from 7-oxanorbornadiene derivatives

A microwave-assisted tandem [3+2] cycloaddition/retro-Diels-Alder reaction of azomethine ylides derived from imines of α-amino esters to dimethyl 7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate derivatives is described. The procedure delivers, in a s

Soluble and polymer-supported 2- and 3-benzylated furans for the preparation of α,β-ethylenic carbonyl compounds

Soluble and polymer-supported 2- and 3-benzylated furans were subjected to a sequence involving a Diels-Alder reaction with α,β-acetylenic carbonyl compounds, a Michael addition, and a subsequent retro-Diels-Alder reaction to yield olefinic compounds. On solid support, this traceless strategy is advantageous since pure compounds were released in the thermal cycloreversion step. The fur-2-ylated resin allowed a highly diastereoselective synthesis.

Stereoselective 1,3-dipolar cycloaddition of a maleate derivative with azomethine ylides derived from α-amino esters: Synthesis of 3-pyrrolines

A new preparation of 3-pyrrolines is described by [3+2] cycloadditions of N-metalated azomethine ylides derived from α-amino esters with a dimethyl 7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate derivative, followed by retro-Diels-Alder reactions. T