31463-28-2

Basic information

• Product Name: N-(Phenylmethylene)tricyclo<3.3.1.1^3,7>decan-1-amine N-Oxide
• Synonyms: N-(Phenylmethylene)tricyclo<3.3.1.1^3,7>decan-1-amine N-Oxide
• CAS NO: 31463-28-2
• Molecular Weight: 255.36
• Mol File: 31463-28-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-(Phenylmethylene)tricyclo<3.3.1.1^3,7>decan-1-amine N-Oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(Phenylmethylene)tricyclo<3.3.1.1^3,7>decan-1-amine N-Oxide(31463-28-2)
• EPA Substance Registry System: N-(Phenylmethylene)tricyclo<3.3.1.1^3,7>decan-1-amine N-Oxide(31463-28-2)

Safety Data

• Hazardous Substances Data: 31463-28-2(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 57527-54-5 N-(-adamantan-1-yl)-1-phenylmethanimine 
• 768-94-5 1-Adamantanamine 
• 57527-59-0 2-(1-adamantyl)-3-phenyloxaziridine 
• 3717-60-0 2-[N-(1-adamantyl)]aminomethylbenzene 
• 31463-23-7 N-adamantylhydroxylamine 
• 935-56-8 1-chloroadamantane 
• 17876-73-2 O-(trimethylsilyl)benzaldoxime 
• 22734-10-7 1-Nitrosoadamantane 

Downstream Products

• 72995-58-5 2-adamantan-1-yl-4-benzyl-3-phenyl-[1,2,4]oxadiazolidine-5-thione 
• 861198-37-0 1-adamantyl-3-methyl-2-phenylazabutane-1-nitroxide 
• 72995-57-4 2-adamantan-1-yl-3,4-diphenyl-[1,2,4]oxadiazolidine-5-thione 

Relevant articles and documents

The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization

Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO. Georg Thieme Verlag Stuttgart.

A Facile One-Step Synthesis of C-Arylnitrones Using Dimethyldioxirane

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Synthesis of Adamantane Derivatives. 49. Substitution Reaction of 1-Adamantyl Chloride with Some Trimethylsilylated Unsaturated Compounds

Catalytic substitution reactions at the adamantane bridgehead were studied by using α,β- and β,γ-unsaturated trimethylsilanes.Treatment of 1-adamantyl (Ad) chloride (1) with allyltrimethylsilane and its heteroanalogues, X=Y-Z-SiMe3, in the presence of Lewis acid as a catalyst gave the products Ad-X-Y=Z, X=Y+(Ad)-Z-, and X=Y-Z-Ad, depending on the attack site of the adamantyl group on each X, Y, and Z atom.Treatment of 1 with (phenylethynyl)trimethylsilane also gave a substituted adamantane in good yield.The substitution reactions of 1 with aryl- and heteroaryltrimethylsilanes under similar conditions occurred at a position distinct from that of acetylation, indicating that adamantylation was not influenced by an electronic effect of the trimethylsilyl group.