31536-21-7

Basic information

• Product Name: isopropyl 4-methylbenzenesulfinate
• Synonyms: isopropyl 4-methylbenzenesulfinate
• CAS NO: 31536-21-7
• Molecular Weight: 198.286
• Mol File: 31536-21-7.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: isopropyl 4-methylbenzenesulfinate(CAS DataBase Reference)
• NIST Chemistry Reference: isopropyl 4-methylbenzenesulfinate(31536-21-7)
• EPA Substance Registry System: isopropyl 4-methylbenzenesulfinate(31536-21-7)

Safety Data

• Hazardous Substances Data: 31536-21-7(Hazardous Substances Data)

Upstream product

• 75-30-9 2-iodo-propane 
• 351186-41-9 4-methyl-N-morpholin-4-ylbenzenesulfonamide 
• 624-31-7 4-tolyl iodide 
• 106-45-6 para-thiocresol 
• 67-63-0 isopropyl alcohol 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 5720-05-8 4-methylphenylboronic acid 
• 536-57-2 p-toluene sulfinic acid 
• 103-19-5 di(p-tolyl) disulfide 
• 31536-19-3 allyl 4-methylbenzenesulfinate 
• 672-78-6 methyl p-toluene sulfinate 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 22598-56-7 isopropyl chlorosulfite 

Downstream Products

• 16066-33-4 4-<(4-methylphenyl)sulfinyl>morpholine 
• 36832-47-0 vinyl-4-tolylsulfoxide 
• 104310-56-7 1-methyl-4-(prop-1-yn-1-ylsulfinyl)benzene 
• 124778-60-5 C₄₇H₅₇NO₄S₃Si 
• 289473-09-2 1-(p-tolylsulfinyl)-2-naphthaldehyde 
• 62351-51-3 2-(p-tolylsulfinyl)benzaldehyde 
• 168332-91-0 1-hexynyl p-tolyl sulfoxide 
• 319913-63-8 phenylacetylenic phenyl sulfoxyde 
• 298693-16-0 1-methyl-4-(oct-1-yne-1-sulfinyl)-benzene 
• 319913-64-9 1-(hept-1-yne-1-sulfinyl)-4-methyl-benzene 
• 320589-21-7 1-(p-tolylsulfinyl)-2-naphthaldehyde dimethyl acetal 
• 124778-58-1 C₄₇H₅₅NO₄S₃Si 
• 1693-83-0 1-Methyl-4-((S)-2-methyl-propane-2-sulfinyl)-benzene 

Relevant articles and documents

Facile aerobic photo-oxidative synthesis of sulfinic esters

A mild and efficient one-pot visible light-induced method has been developed for the synthesis of sulfinic esters. Sulfinic esters are important structural elements that are frequently found in pharmaceutical agents and biologically active natural products. The routine procedure in the drug discovery and development process to prepare and fully characterize sulfinic esters make them a drug candidate for biological evaluation.

Electrochemical Synthesis of Sulfinic Esters via Aerobic Oxidative Esterification of Thiophenols with Alcohols

A method for the electrochemical synthesis of sulfinic esters by aerobic oxidative coupling of thiophenols and alcohols has been developed. Using electrons as the redox reagent and O 2in air as the oxygen source, the reactions proceeded smoothly at room temperature, even for a gram-scale preparation. No use of catalyst, clean redox reagent, green and abundant oxygen source, and mild reaction conditions make this strategy eco-friendl.

Electrochemical synthesis of sulfinic esters from alcohols and thiophenols

Electrochemical oxidative couplings between S[sbnd]H and O[sbnd]H bonds are achieved herein directly from readily-available alcohols and thiophenols, affording a series of diverse sulfinic esters. This strategy can take advantage of 6 equivalents of alcohol, relative to thiophenol, to achieve moderate to good yields, without the assistance of any metallic catalysts, bases, and additional oxidants.