31682-65-2Relevant academic research and scientific papers
AN ELECTRON SPIN RESONANCE STUDY OF THE REACTIONS OF PHOSPHORUS CENTERED RADICALS WITH THIOKETONES
McGimpsey, W. Grant,Depew, M. Catherine,Swan, J. K. S.
, p. 135 - 144 (2007/10/02)
The utility of thioketones as traps for intermediate phosphorus-centered radicals is illustrated by an e.s.r. study of the phosphorus-thioketone radical adducts.The direct evidence of the P-S bond formation in the adduct is clearly supported by the large phosphorus hyperfine splittings which vary with the nature of the organophosphorus moiety.The method also readily detects in the organophosphorus compounds which are susceptible to thermal oxidation.The direct photochemical reactions of thioketones with dialkoxyphosphites are shown to involve free radical mechanisms.
