32122-11-5

Basic information

• Product Name: METHYL 4-BENZYLOXYBENZOATE
• Synonyms: METHYL 4-(BENZYLOXY)BENZENECARBOXYLATE;METHYL 4-BENZYLOXYBENZOATE;LABOTEST-BB LT00455680;4-BENZYLOXYBENZOIC ACID METHYL ESTER;RARECHEM AL BF 0087;METHYL 4-BENZYLOXYBENZONATE;4-Methylbenzoicacidbenzyloxygenradicals
• CAS NO: 32122-11-5
• Molecular Formula: C₁₅H₁₄O₃
• Molecular Weight: 242.27
• Product Categories: Aromatic Esters
• Mol File: 32122-11-5.mol
• Article Data: 65

Chemical Properties

• Melting Point: 99°C
• Boiling Point: 372.5°Cat760mmHg
• Flash Point: 156.2°C
• Appearance: /
• Density: 1.142g/cm³
• Vapor Pressure: 9.56E-06mmHg at 25°C
• Refractive Index: 1.566
• Solubility: soluble in Acetone
• BRN: 2119212
• CAS DataBase Reference: METHYL 4-BENZYLOXYBENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 4-BENZYLOXYBENZOATE(32122-11-5)
• EPA Substance Registry System: METHYL 4-BENZYLOXYBENZOATE(32122-11-5)

Safety Data

• Safety Statements: 22-24/25
• RIDADR: 3077
• Hazardous Substances Data: 32122-11-5(Hazardous Substances Data)

Usage

Chemical Properties

White solid

InChI:InChI=1/C15H14O3/c1-17-15(16)13-7-9-14(10-8-13)18-11-12-5-3-2-4-6-12/h2-10H,11H2,1H3

Upstream product

• 100-44-7 benzyl chloride 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 100-51-6 benzyl alcohol 
• 67-56-1 methanol 
• 836-43-1 4-benzyloxybenzyl alcohol 
• 1486-50-6 4-(benzyloxy)benzoic acid chloride 
• 100-39-0 benzyl bromide 
• 19578-68-8 4-(4-benzyloxyphenyl) iodide 
• 540-38-5 p-Iodophenol 
• 108-88-3 toluene 
• 91608-15-0 tris(2,4,6-trimethoxyphenyl)phosphine 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 1589-82-8 phenylmagnesium bromide 
• 4397-53-9 p-benzyloxybenzaldehyde 

Downstream Products

• 836-43-1 4-benzyloxybenzyl alcohol 
• 84403-51-0 4-(benzyloxy)-N-methylbenzamide 
• 312631-23-5 4-benzyloxy-benzoic acid tert-butyl ester 
• 58995-82-7 2-(4-benzyloxyphenyl)-1H-indole 
• 24262-66-6 methyl 4-acetoxybenzoate 
• 1227068-73-6 benzothiazol-2-yl-(4-benzyloxy-phenyl)methanone 
• 1445854-36-3 3-(4-(benzyloxy)phenyl)pentan-3-ol 
• 1445854-37-4 4-(3-(4-(benzyloxy)phenyl)pentan-3-yl)-2-methylphenol 
• 1445854-38-5 1-(4-(3-(4-(benzyloxy)phenyl)pentan-3-yl)-2-methylphenoxy)-3,3-dimethylbutan-2-one 
• 1445854-39-6 1-(4-(3-(4-(benzyloxy)phenyl)pentan-3-yl)-2-methylphenoxy)-3,3-dimethylbutan-2-ol 
• 1445854-40-9 4-(3-(4-(2-hydroxy-3,3-dimethylbutoxy)-3-methylphenyl)-pentan-3-yl)phenol 
• 1445854-41-0 ethyl 2-(4-(3-(4-(2-hydroxy-3,3-dimethylbutoxy)-3-methylphenyl)pentan-3-yl)phenoxy)acetate 
• 1445853-70-2 N-hydroxy-2-(4-(3-(4-(2-hydroxy-3,3-dimethylbutoxy)-3-methylphenyl)pentan-3-yl)phenoxy)acetamide 
• 1445854-50-1 1-(4-(3-(4-hydroxyphenyl)pentan-3-yl)-2-methylphenoxy)-3,3-dimethylbutan-2-one 

Relevant articles and documents

A “universal” catalyst for aerobic oxidations to synthesize (hetero)aromatic aldehydes, ketones, esters, acids, nitriles, and amides

Functionalized (hetero)aromatic compounds are indispensable chemicals widely used in basic and applied sciences. Among these, especially aromatic aldehydes, ketones, carboxylic acids, esters, nitriles, and amides represent valuable fine and bulk chemicals, which are used in chemical, pharmaceutical, agrochemical, and material industries. For their synthesis, catalytic aerobic oxidation of alcohols constitutes a green, sustainable, and cost-effective process, which should ideally make use of active and selective 3D metals. Here, we report the preparation of graphitic layers encapsulated in Co-nanoparticles by pyrolysis of cobalt-piperazine-tartaric acid complex on carbon as a most general oxidation catalyst. This unique material allows for the synthesis of simple, functionalized, and structurally diverse (hetero)aromatic aldehydes, ketones, carboxylic acids, esters, nitriles, and amides from alcohols in excellent yields in the presence of air.

Electro-Oxidative Selective Esterification of Methylarenes and Benzaldehydes

A mild and green electro-oxidative protocol to construct aromatic esters from methylarenes and alcohols is herein reported. Importantly, the reaction is free of metals, chemical oxidants, bases, acids, and operates at room temperature. Moreover, the design of the electrolyte was found critical for the oxidation state and structure of the coupling products, a rarely documented effect. This electro-oxidative coupling process also displays exceptional tolerance of many fragile easily oxidized functional groups such as hydroxy, aldehyde, olefin, alkyne, as well as neighboring benzylic positions. The enantiomeric enrichment of some chiral alcohols is moreover preserved during this electro-oxidative coupling reaction, making it overall a promising synthetic tool.

Cannabidiol derivative, preparation method and application thereof

The invention discloses a cannabidiol derivative, a preparation method and application thereof, and belongs to the technical field of medicinal chemistry, wherein the cannabidiol derivative is obtained by taking cannabidiol as a main body through a synthesis means, and an anti-tumor activity determination result shows that the cannabidiol derivative prepared by the invention has an inhibition effect on lung cancer cell strains, human breast cancer cell strains, nasopharynx cancer and drug-resistant strains thereof.