32268-44-3Relevant academic research and scientific papers
Alkene Oxyalkylation Enabled by Merging Rhenium Catalysis with Hypervalent Iodine(III) Reagents via Decarboxylation
Wang, Yin,Zhang, Lei,Yang, Yunhui,Zhang, Ping,Du, Zhenting,Wang, Congyang
supporting information, p. 18048 - 18051 (2014/01/06)
Rhenium-catalyzed oxyalkylation of alkenes is described, where hypervalent iodine(III) reagents derived from widely occurring aliphatic carboxylic acids were used as, for the first time, not only an oxygenation source but also an alkylation source via decarboxylation. The reaction also features a wide substrate scope, totally regiospecific difunctionalization, mild reaction conditions, and ready availability of both substrates. Mechanistic studies revealed a decarboxylation/radical-addition/cation-trapping cascade operating in the reaction.
Stereochemistry of Ring Opening of trans-1,2-Diphenylcyclopropanes by Mercury(II)salts
Bandaev, S. G.,Sabarov, Yu. S.,Hantschmann, A.,Weissenfels, M.
, p. 643 - 648 (2007/10/02)
Reaction of trans-1,2-diphenylcyclopropanes 1 and 2 with mercuric salts yields diastereomeric 1,2-diphenylpropanole derivatives.The ratio of erythro and threo diastereomers depends on the nature of substituents and solvent properties.A mechanism is propos
