32446-40-5

Usage

Safety Profile

Poison by subcutaneous andintraperitoneal routes. When heated to decomposition it emits toxicfumes of NOx and SOx.

InChI:InChI=1/C6H11NS/c1-2-3-4-5-8-6-7/h2-5H2,1H3

Upstream product

• 110-53-2 1-Bromopentane 
• 333-20-0 potassium thioacyanate 
• 543-59-9 1-Chloropentane 
• 540-72-7 sodium thiocyanide 
• 4450-76-4 1-pentyl tosylate 

Downstream Products

• 6303-18-0 n-pentanesulphonyl chloride 
• 53310-48-8 2-Pentylthio-2-phenylpropanitril 
• 112-51-6 diamyl disulfide 
• 110-66-7 n-pentanethiol 

Relevant academic research and scientific papers

Ionic liquid brush as a highly efficient and reusable catalyst for on-water nucleophilic substitutions

A very efficient and reusable catalyst has been developed for the on-water nucleophilic substitution of alkyl halides and tosylates with azide or thiocyanate in excellent to quantitative yields. The reaction proceeds smoothly and cleanly without any organic cosolvent or other adductive, and the brush can be reused at least 10 times without noticeable loss of the catalytic activity. The high efficiency, simplicity of product and catalyst isolation, outstanding recyclability, and organic-solvent-free conditions show promise for the use of this catalyst in the laboratory and in industry. A highly efficient and reusable ionic liquid brush catalyst has been developed for the on-water nucleophilic substitution of alkyl halides and tosylates with azide or thiocyanate in excellent to quantitative yields without any organic cosolvent or other adductive. The catalyst can be reused at least 10 times without noticeable loss of the catalytic activity. Copyright

2-Hydroxy-N,N,N-tributylethanaminium thiocyanate as solvent and reagent for the preparation of alkyl thiocyanates

2-Hydroxy-N,N,N-tributylethanaminium thiocyanate was utilized as both solvent and reagent for the conversion of alkyl halides to the corresponding alkyl thiocyanates in good yields under mild conditions.

Organoclay triphase catalysts

In a method of carrying out organic conversions via heterogeneous phase transfer catalysis by contacting immiscible liquid phases containing respective substances capable of interacting, with a solid catalyst to promote the transfer of reactive species from one liquid phase to another, the improvement comprises employing as catalyst a cation exchanged form of a 2:1 layered silicate clay with layer charge densities in the range of above 0.4 to 2.0 containing an onium ion containing one or more alkyl hydrocarbon chains and maintaining the materials in emulsified form by having a sufficient chain length of an alkyl group relative to the charge density of the clay.

COMPARISON OF UNSTIRRED, SONICATED AND STIRRED MIXTURES ON THE TWO-PHASE DISPLACEMENT OF HALIDE BY THIOCYANATE ION

The two-phase catalytic reaction of alkyl halides with aqueous thiocyanate ion has been found to proceed readily in stirred, unstirred, and sonicated solutions.