32446-40-5

Basic information

• Product Name: N-AMYL THIOCYANATE
• Synonyms: N-AMYL THIOCYANATE;Thiocyanic acid，amyl ester;amyl rhodanate;amyl rhodanide;amyl thiocyanate;Pentyl thiocyanate;Thiocyanic acid pentyl ester
• CAS NO: 32446-40-5
• Molecular Formula: C₆H₁₁NS
• Molecular Weight: 129.22324
• Mol File: 32446-40-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 165°C (estimate)
• Flash Point: 75.8°C
• Appearance: /
• Density: 0.955 (estimate)
• Vapor Pressure: 0.304mmHg at 25°C
• Refractive Index: 1.5500 (estimate)
• CAS DataBase Reference: N-AMYL THIOCYANATE(CAS DataBase Reference)
• NIST Chemistry Reference: N-AMYL THIOCYANATE(32446-40-5)
• EPA Substance Registry System: N-AMYL THIOCYANATE(32446-40-5)

Safety Data

• Hazardous Substances Data: 32446-40-5(Hazardous Substances Data)

Usage

Safety Profile

Poison by subcutaneous andintraperitoneal routes. When heated to decomposition it emits toxicfumes of NOx and SOx.

InChI:InChI=1/C6H11NS/c1-2-3-4-5-8-6-7/h2-5H2,1H3

Upstream product

• 110-53-2 1-Bromopentane 
• 333-20-0 potassium thioacyanate 
• 540-72-7 sodium thiocyanide 
• 4450-76-4 1-pentyl tosylate 
• 543-59-9 1-Chloropentane 

Downstream Products

• 6303-18-0 n-pentanesulphonyl chloride 
• 53310-48-8 2-Pentylthio-2-phenylpropanitril 
• 110-66-7 n-pentanethiol 
• 112-51-6 diamyl disulfide 

Relevant articles and documents

Ionic liquid brush as a highly efficient and reusable catalyst for on-water nucleophilic substitutions

A very efficient and reusable catalyst has been developed for the on-water nucleophilic substitution of alkyl halides and tosylates with azide or thiocyanate in excellent to quantitative yields. The reaction proceeds smoothly and cleanly without any organic cosolvent or other adductive, and the brush can be reused at least 10 times without noticeable loss of the catalytic activity. The high efficiency, simplicity of product and catalyst isolation, outstanding recyclability, and organic-solvent-free conditions show promise for the use of this catalyst in the laboratory and in industry. A highly efficient and reusable ionic liquid brush catalyst has been developed for the on-water nucleophilic substitution of alkyl halides and tosylates with azide or thiocyanate in excellent to quantitative yields without any organic cosolvent or other adductive. The catalyst can be reused at least 10 times without noticeable loss of the catalytic activity. Copyright

Organoclay triphase catalysts

In a method of carrying out organic conversions via heterogeneous phase transfer catalysis by contacting immiscible liquid phases containing respective substances capable of interacting, with a solid catalyst to promote the transfer of reactive species from one liquid phase to another, the improvement comprises employing as catalyst a cation exchanged form of a 2:1 layered silicate clay with layer charge densities in the range of above 0.4 to 2.0 containing an onium ion containing one or more alkyl hydrocarbon chains and maintaining the materials in emulsified form by having a sufficient chain length of an alkyl group relative to the charge density of the clay.

Preparation and Synthetic Utility of Phase-Transfer Catalysts Anchored to Polystyrene

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