32569-84-9

Upstream product

• 591-50-4 iodobenzene 
• 42345-82-4 (E)-1,2-dichloro-1-ethoxy-ethene 
• 23268-50-0 Ethyl(trimethylstannylethinyl)ether 
• 137344-20-8 ethoxy(tributylstannyl)acetylene 
• 67500-35-0 1-ethoxy-2-iodoacetylene 
• 13049-42-8 phenylketene diethylacetal 
• 71-43-2 benzene 
• 536-74-3 phenylacetylene 
• 1483-82-5 phenylethynyl chloride 
• 141-52-6 sodium ethanolate 
• 24648-07-5 2-Phenyl-1,3,3-trichlorocyclopropene 
• 156336-58-2 2-Ethoxy-3-phenylcyclopropenone 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 36678-63-4 ethoxyethynylmagnesium bromide 

Downstream Products

• 19307-81-4 β,β-Dichlor-α-phenyl-acrolein-semicarbazon 
• 1603-79-8 phenylglyoxylic acid ethyl ester 
• 101-97-3 Ethyl 2-phenylethanoate 
• 81269-64-9 3-phenylphenanthro[9,10-b]furan-2(3H)-one 
• 1174523-96-6 (R)-8a-(but-3-enyl)-5-ethoxy-6-phenyl-2,3,8,8a-tetrahydroindolizin-7(1H)-one 
• 1174524-05-0 (S)-7-ethoxy-6-phenyl-2,3,8,8a-tetrahydroindolizin-5(1H)-one 
• 1174523-95-5 (R)-5-ethoxy-6-phenyl-2,3,8,8a-tetrahydroindolizin-7(1H)-one 
• 1322084-84-3 C₁₇H₂₃ClO 
• 1322084-28-5 C₂₀H₂₂O 
• 1322084-96-7 C₁₉H₂₄O 
• 1322084-30-9 C₁₈H₁₈O 
• 1322084-88-7 C₁₄H₁₇ClO 
• 1322084-92-3 C₁₃H₁₅BrO 
• 14815-74-8 ethyl 2-phenylpent-4-enoate 

Relevant academic research and scientific papers

Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols

Reported herein is a general and efficient dual-deoxygenative coupling of primary alcohols with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcohols using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcohols (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence.

Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions

The previously unexplored metal-catalyzed [5 + 2] cycloadditions of vinylcyclopropanes (VCPs) and electron-rich alkynes (ynol ethers) have been found to provide a highly efficient, direct route to dioxygenated seven-membered rings, a common feature of num

Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines

Platinum-catalyzed formal [5+2] and [4+2] annulations of isoxazoles with heterosubstituted alkynes enabled the atom-economical synthesis of valuable 1,3-oxazepines and 2,5-dihydropyridines, respectively. Importantly, this Pt catalysis not only led to unique reactivity dramatically divergent from that observed under Au catalysis, but also proceeded via unprecedented α-imino platinum carbene intermediates.

Synthesis of ethoxyethynylarenes by the palladium-catalyzed reaction of aryl iodides with ethoxy(trialkylstannyl)acetylenes

Palladium-catalyzed reaction of aryl and heteroaryl iodides with ethoxy(trialkylstannyl)acetylenes gave the ethoxyethynylarenes and -heteroarenes, which were easily transformed by hydration reaction into ethyl areneacetates and heteroareneacetates.

Alkoxyacetylenes from alkyl 1,2-dichlorovinyl ethers

Alkyl 1,2-dichlorovinyl ethers 4, prepared from sodium alkoxides 1 and trichloroethylene 2, react in tetrahydrofuran with two equivalents of butyllithium to afford lithium alkoxyacetylides 5. On the one hand, these acetylides react with ketones or dichlor

Ru-CATALYZED OXIDATION OF SUBSTITUTED ACETYLENES TO α-KETO ESTERS AND α-KETO AMIDES WITH IODOSYLBENZENE

Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Ru-catalysts affords α-keto esters and α-keto amides in 44-84percent yield.These conversions can also be effected with RuO4.