328-73-4

Basic information

• Product Name: 3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE
• Synonyms: MBT-I;1,3-BIS(TRIFLUOROMETHYL)-5-IODOBENZENE;1-IODO-3,5-BIS(TRIFLUOROMETHYL)BENZENE;1-IODO-3,5-DI(TRIFLUOROMETHYL)BENZENE;3,5-BIS(TRIFLUOROMETHYL)-1-IODO BENZENE;3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE;TIMTEC-BB SBB006562;3,5-Bis(trifluoromethyl)iodobenzene 97%
• CAS NO: 328-73-4
• Molecular Formula: C₈H₃F₆I
• Molecular Weight: 340
• Product Categories: Fluoro-contained Iodo series;Aromatic Hydrocarbons (substituted) & Derivatives;Miscellaneous;Aryl;C8;Halogenated Hydrocarbons;Trifluoromethy ada@tuskwei.com whatsapp;+8618031153937
• Mol File: 328-73-4.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 59-61 °C10 mm Hg(lit.)
• Flash Point: 166 °F
• Appearance: clear light pink to yellow liquid
• Density: 1.919 g/mL at 25 °C(lit.)
• Vapor Pressure: 1.03mmHg at 25°C
• Refractive Index: n20/D 1.463(lit.)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility: Slightly soluble in water.
• Sensitive: Light Sensitive
• BRN: 2461627
• CAS DataBase Reference: 3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE(328-73-4)
• EPA Substance Registry System: 3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE(328-73-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 328-73-4(Hazardous Substances Data)

Usage

Chemical Properties

clear light pink to yellow liquid

Uses

3,5-bis(trifluoromethyl)pheny1- magnesium iodide was prepared from 1-iodo-3,5- bis(trifluoromethyl)benzene. Monodeprotected masked hexayne was not particularly stable and hence was used directly without purification in a Sonogashira coupling with 1-iodo-3,5-bis(trifluoromethyl)benzene to provide mono-aryl-end-capped masked hexayne.

General Description

1-Iodo-3,5-bis(trifluoromethyl)benzene is a halogenated hydrocarbon.

InChI:InChI=1/C8H3F6I/c9-7(10,11)4-1-5(8(12,13)14)3-6(15)2-4/h1-3H

Synthetic route

1,3-bis(trifluoromethyl)benzene (402-31-3) → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With sulfuric acid; iodine; fluorine In 1,1,2-Trichloro-1,2,2-trifluoroethane Ambient temperature;	83%
Multi-step reaction with 3 steps 1: disulfuric acid; sulfuric acid; nitric acid 2: tin (II)-chloride; aqueous hydrochloric acid / Hydrogenation 3: aqueous hydrochloric acid; sodium nitrite; potassium iodide View Scheme
Multi-step reaction with 2 steps 1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4′-di-(tert-butyl)-2,2′-bipyridyl / tetrahydrofuran / 24 h / 80 °C / High pressure; Inert atmosphere 2: 1,10-Phenanthroline; copper(l) iodide; potassium iodide / methanol; water / 3 h / 80 °C / High pressure View Scheme

3,5-Bis-(trifluoromethyl)aniline (328-74-5) → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
Stage #1: 3,5-Bis-(trifluoromethyl)aniline With diiodomethane; sodium nitrite In dichloromethane; water at 23℃; for 0.0833333h; Stage #2: With acetic acid In dichloromethane; water at 23℃; for 1h;	82%
With hydrogenchloride; potassium iodide; sodium nitrite
(i) NaNO2, aq. HCl, (ii) CuI; Multistep reaction;
Stage #1: 3,5-Bis-(trifluoromethyl)aniline With toluene-4-sulfonic acid In acetonitrile at 20℃; for 0.166667h; Stage #2: With potassium iodide; sodium nitrite In water; acetonitrile at 0 - 20℃;

3,6-bis(trifluoromethyl)bromobenzene (328-70-1) → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With iodine; sodium iodide In acetonitrile at 20℃; for 36h; Inert atmosphere; UV-irradiation; Green chemistry;	76%

1,3-bis(trifluoromethyl)benzene (402-31-3) → 3-(trifluoromethyl)benzoic acid (454-92-2) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With sulfuric acid; iodine for 7h; Ambient temperature;	A 8% B 70%

1,3-bis(trifluoromethyl)benzene (402-31-3) → 3-iodo-5-(trifluoromethyl)benzoic acid (28186-62-1) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With sulfuric acid; iodine at 55℃; for 7h;	A 18% B 52%

1-nitro-3,5-bis(trifluoromethyl)benzene (328-75-6) → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
Multi-step reaction with 2 steps 1: tin (II)-chloride; aqueous hydrochloric acid / Hydrogenation 2: aqueous hydrochloric acid; sodium nitrite; potassium iodide View Scheme

meta-sodium bisulfate + 3,6-bis(trifluoromethyl)bromobenzene (328-70-1) → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With n-butyllithium; iodine In tetrahydrofuran; water

2-(3,5-bis-trifluoromethyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane (69807-91-6) → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With copper(l) iodide; 1,10-Phenanthroline; potassium iodide In methanol; water at 80℃; for 3h; High pressure;	0.266 g

(3,5-bis(trifluoromethyl)phenyl)(cyano)-l3-iodanyl trifluoromethanesulfonate → 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; iron(II) acetate In 1,2-dichloro-ethane at 20℃; for 4h; Inert atmosphere; Sealed tube;

1-iodo-4-n-propylbenzene (126261-84-5) + 3,5-bis(trifluoromethyl)phenyl carboxylic acid chloride (785-56-8) → 4-propylbenzoyl chloride (52710-27-7) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4)

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 100℃; for 12h; Time;

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + (2-iodo-5-methoxyphenyl)boronic acid (89694-50-8) → 2-(3,5-bis(trifluoromethyl)phenyl)-4-methoxyiodobenzene (1227633-25-1)

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene at 80℃; Suzuki-Miyaura cross-coupling; Inert atmosphere; chemoselective reaction;	100%

thiophene boronic acid (6165-68-0) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 1-(2-thienyl)-3,5-bis(trifluoromethyl)benzene

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

benzo[b]thiophene-2-boronic acid (98437-23-1) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 2-(3,5-bis-trifluoromethyl-phenyl)-benzo[b]thiophene

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

(E)-1-hexenyldihydroxyborane (42599-18-8) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 1-((E)-Hex-1-enyl)-3,5-bis-trifluoromethyl-benzene

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

thianthren-1-yl boronic acid (108847-76-3) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 1-(3,5-bis-trifluoromethyl-phenyl)-thianthrene

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 2-Methylphenylboronic acid (16419-60-6) → 2-methyl-3',5'-bis(trifluoromethyl)biphenyl

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + m-tolylboronic acid (17933-03-8) → 3'-methyl-3,5-bis(trifluoromethyl)-1,1'-biphenyl

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 4-methylphenylboronic acid (5720-05-8) → 4’-methyl-3,5-bis(trifluoromethyl)-1,1’-biphenyl

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 4-Chlorophenylboronic acid (1679-18-1) → 4'-chloro-3,5-bis(trifluoromethyl)-1,1'-biphenyl

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 4-methoxyphenylboronic acid (5720-07-0) → 3,5-bis(trifluoromethyl)-4’-methoxybiphenyl

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%
With potassium phosphate monohydrate; 4,4'-di-tBu-2,2'-dipyridylpalladium(II) dichloride In methanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;	94%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 1-Naphthylboronic acid (13922-41-3) → 1-(3,5-bis(trifluoromethyl)phenyl)naphthalene

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 4-trifluoromethylphenylboronic acid (128796-39-4) → 4-trifluoromethyl-3',5'-bis(trifluoromethyl)biphenyl (460743-64-0)

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + phenylboronic acid (98-80-6) → 3,5-bis(trifluoromethyl)biphenyl (336621-50-2)

Conditions	Yield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%
With potassium phosphate monohydrate; 4,4'-di-tBu-2,2'-dipyridylpalladium(II) dichloride In methanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;	97%
Stage #1: 3,5-bis(trifluoromethyl)iodobenzene; phenylboronic acid With potassium phosphate In 1,2-dimethoxyethane at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Stage #2: In 1,2-dimethoxyethane; water at 100℃; for 10h;	91%

3',5'-di-O-acetyl-3-buta-2,3-dien-1-ylthymidine (1415409-75-4) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 3,3'-{iminobis[(2Z)-3-(3,5-bis(trifluoromethyl)phenyl)but-2-ene-4,1-diyl]}bis(3',5'-di-O-acetylthymidine) (1426070-48-5)

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane; ammonium tartrate; potassium carbonate In 1,4-dioxane; N,N-dimethyl-formamide at 100℃; for 8h; stereoselective reaction;	99%

4-tolyl iodide (624-31-7) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → (3,5-bis(trifluoromethyl)phenyl)(p-tolyl)sulfane (1262439-96-2)

Conditions	Yield
Stage #1: 4-tolyl iodide With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 100℃; for 8h; Inert atmosphere; Stage #2: 3,5-bis(trifluoromethyl)iodobenzene In water; dimethyl sulfoxide; N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere;	98%
Stage #1: 4-tolyl iodide With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 100 - 110℃; for 8h; Inert atmosphere; Stage #2: 3,5-bis(trifluoromethyl)iodobenzene In water; dimethyl sulfoxide; N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere;	98%

4-hydroxy[1]benzopyran-2-one (1076-38-6) + 1,2-propanediene (463-49-0) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 3-{2-[3,5-bis(trifluoromethyl)phenyl]prop-2-en-1-yl}-4-hydroxy-2H-chromen-2-one

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In acetonitrile at 65℃; under 760.051 Torr; for 20h;	97%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + trifluoroacetic anhydride (407-25-0) → (3,5-bis(trifluoromethyl)phenyl)-λ3-iodanediyl bis(2,2,2-trifluoroacetate)

Conditions	Yield
Stage #1: trifluoroacetic anhydride With dihydrogen peroxide In dichloromethane; water at -50℃; for 0.166667h; Stage #2: 3,5-bis(trifluoromethyl)iodobenzene In dichloromethane; water at 15℃; for 14h;	97%
With dihydrogen peroxide In dichloromethane at -50 - 15℃; for 16h; Schlenk technique; Inert atmosphere;

1-(4-methoxyphenyl)-p-carborane + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 1-[3,5-bis(trifluoromethyl)phenyl]-12-(4-methoxyphenyl)-p-carborane

Conditions	Yield
With BuLi; CuCl; pyridine In pyridine; 1,2-dimethoxyethane; hexane (N2); addn. of BuLi in hexanes to the p-carborane derivative in DME withstirring, addn. of pyridine and CuCl with vigorous stirring, reflux (ca . 30 min), addn. of the aryl iodide, gentle reflux (95-100°C, 24 h); addn. of Et2O/H2O, set aside (overnight), sepn. of a solid, recrystn. (EtOH); elem. anal.;	96%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 1,1’-bis[3,5-bis(trifluoromethyl)phenyl]sulfide

Conditions	Yield
With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere;	96%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 3,5-bis-(trifluoromethyl)phenol (349-58-6)

Conditions	Yield
With water; ethylene glycol; potassium hydroxide; copper dichloride In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere;	96%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + tert-butyl (3-methylbenzyl)(3-methylpyridin-2-yl)carbamate → tert-butyl ((5-methyl-3',5'-bis(trifluoromethyl)-[1,1'-biphenyl]-3-yl)methyl)(3-methylpyridin-2-yl)carbamate

Conditions	Yield
With methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate; silver(I) acetate; palladium diacetate; 3-(trifluoromethyl)pyridine-2-(1H)-one In chloroform at 100℃; for 24h;	96%

1,3-dimethylbarbituric acid (769-42-6) + 1,2-propanediene (463-49-0) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 5,5-bis{2-[3,5-bis(trifluoromethyl)phenyl]prop-2-en-1-yl}-1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione

Conditions	Yield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 80℃; under 750.075 Torr; for 20h;	95%

o-methylphenylacetic acid (644-36-0) + 3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 2-(4-methyl-3',5'-bis(trifluoromethyl)-[1,1'-biphenyl]-3-yl)acetic acid

Conditions	Yield
With dipotassium hydrogenphosphate; methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate; (3r,5r,7r)-N-(2-hydroxy-5-(trifluoromethyl)pyridin-3-yl)adamantane-1-carboxamide; palladium diacetate; silver carbonate at 100℃; for 24h;	95%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + trifluoroacetic acid (76-05-1) → (3,5-bis(trifluoromethyl)phenyl)-λ3-iodanediyl bis(2,2,2-trifluoroacetate)

Conditions	Yield
With Oxone In chloroform at 20℃; for 1.5h;	94%
With dipotassium peroxodisulfate In dichloromethane at 36 - 38℃; for 20h;	36%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + tert-butyl ((4-methoxy-3,5-dimethylpyridin-2-yl)methyl)(m-tolyl)carbamate → tert-butyl ((4-methoxy-3,5-dimethylpyridin-2-yl)methyl)(5 methyl-3’,5’-bis(trifluoromethyl)-[1,1’-biphenyl]-3-yl)carbamate

Conditions	Yield
With N-(2-hydroxypyridin-3-yl)acetamide; methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate; silver(I) acetate; palladium diacetate In 1,2-dichloro-ethane at 100℃; for 24h;	94%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + 4-nitro-aniline (100-01-6) → C14H8F6N2O2

Conditions	Yield
With silver hexafluoroantimonate; chloro[di(1-adamantyl)-2-dimethylaminophenylphosphine]gold(I) In methanol at 0 - 80℃; Inert atmosphere;	94%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + phenylacetylene (536-74-3) → 1-(3,5-bis(trifluoromethyl)phenyl)-2-phenylacetylene

Conditions	Yield
With sodium hydroxide In methanol at 80℃; for 12h; Sonogashira Cross-Coupling; Schlenk technique;	92%
With potassium phosphate tribasic trihydrate In methanol at 80℃; for 4h; Sonogashira coupling; Inert atmosphere;	90%
With palladium diacetate; potassium carbonate In ethanol at 80℃; for 24h;	87%
With [{Pd(μ-Cl){κ2-P,C-P(iPr)2(OC6H3-2-Ph)}}2]; triethylamine In water at 40℃; for 4h; Sonogashira coupling; Inert atmosphere;	83%
With [Cu(DMEDA)2]Cl2*H2O; caesium carbonate; N,N`-dimethylethylenediamine In 1,4-dioxane; methanol at 135℃; for 22h; Castro-Stephens reaction; Inert atmosphere;

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + N-(cyclopropylmethyl)-1,1,1-trifluoromethanesulfonamide (357383-42-7) → N-((2-(3,5-bis(trifluoromethyl)phenyl)cyclopropyl)methyl)-1,1,1-trifluoromethanesulfonamide

Conditions	Yield
With t-Boc-L-valine; sodium 2,2,2-trifluoroacetate; palladium diacetate; silver carbonate In tert-butyl alcohol at 80℃; for 18h; Sealed tube; enantioselective reaction;	92%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) + propargyl 2-azidobenzoate → C18H10F6N4O

Conditions	Yield
With cuprous oxide; caesium carbonate In water at 80℃; Sonication; Green chemistry;	92%

3,5-bis(trifluoromethyl)iodobenzene (328-73-4) → 1-iodyl-3,5-bis(trifluoromethyl)benzene

Conditions	Yield
Stage #1: 3,5-bis(trifluoromethyl)iodobenzene With peracetic acid In acetic acid at 40℃; for 1h; Stage #2: ruthenium trichloride In water; acetic acid at 40℃; for 16h;	91%
Stage #1: 3,5-bis(trifluoromethyl)iodobenzene With dihydrogen peroxide; acetic anhydride at 40℃; for 1h; Inert atmosphere; Stage #2: With ruthenium trichloride In water at 40℃; for 16h; Inert atmosphere;	91%

Upstream product

• 328-70-1 3,6-bis(trifluoromethyl)bromobenzene 
• 126261-84-5 1-iodo-4-n-propylbenzene 
• 785-56-8 3,5-bis(trifluoromethyl)phenyl carboxylic acid chloride 
• 69807-91-6 2-(3,5-bis-trifluoromethyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 402-31-3 1,3-bis(trifluoromethyl)benzene 
• 328-74-5 3,5-Bis-(trifluoromethyl)aniline 
• 328-75-6 1-nitro-3,5-bis(trifluoromethyl)benzene 

Downstream Products

• 67570-38-1 α,α-dimethyl-3,5-bis(trifluoromethyl)benzenemethanol 
• 618092-28-7 1-(3,5-(trifluoromethyl)phenyl)-2-(trimethylsilyl)acetylene 
• 172414-69-6 2-(3,5-bis-trifluoromethyl-phenyl)-indene 
• 1008756-45-3 C₂₈H₂₀F₆O₂S 
• 334948-79-7 (CH₃)2NC₂H₄N(CH₃)2PdI(C₆H₃(CF₃)2) 
• 334948-82-2 (C₁₀H₆(CH₃)2N₂)PdI(C₆H₃(CF₃)2) 
• 848465-36-1 [PdI₂(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))] 
• 328-74-5 3,5-Bis-(trifluoromethyl)aniline 
• 1313735-01-1 3,5-bis(trifluoromethyl)phenyl 4-tert-butylphenyl ether 
• 334948-86-6 (CH₃)2NC₂H₄N(CH₃)2Pd(C₆H₃(CF₃)2)(CH₃CN)⁽¹⁺⁾*BF₄^(1-)=(CH₃)4N₂C₂H₄Pd(C₆H₃(CF₃)2)(CH₃CN)BF₄ 
• 334948-88-8 (CH₃)2NC₂H₄N(CH₃)2Pd(C₆H₃(CF₃)2)(CH₃COCH₃)⁽¹⁺⁾*BF₄^(1-)=(CH₃)4N₂C₂H₄Pd(C₆H₃(CF₃)2)(CH₃COCH₃)BF₄ 

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