328012-09-5Relevant articles and documents
Hypervalent iodine in synthesis. 65: A new route to synthesize N-acylbenzotriazoles via palladium catalyzed carbonylation of benzotriazole and hypervalent iodonium salts in the presence of carbon monoxide
Wang,Chen
, p. 1633 - 1637 (2001)
N-acylbenzotriazoles are obtained directly in fair yields by palladium-catalyzed carbonylation of diaryliodonium salts with benzotriazoles in the presence of carbon monoxide.
An efficient one-pot synthesis of: N, N ′-disubstituted ureas and carbamates from N -acylbenzotriazoles
Singh, Anoop S.,Kumar, Dhananjay,Mishra, Nidhi,Tiwari, Vinod K.
, p. 84512 - 84522 (2016/10/12)
A facile and high-yielding one-pot synthesis of carbamates and N,N′-disubstituted symmetrical ureas from N-acylbenzotriazoles has been devised. It is believed that, the intermediate acyl-azide undergo Curtius rearrangement and in different solvents gives different products i.e. carbamates in alcohols and N,N′-disubstituted symmetrical urea in THF.
NEW GUANIDINE DERIVATIVES IN CINNAMIC SERIES
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Paragraph 0049; 0050; 0051, (2013/07/05)
The invention relates to novel guanidine derivatives in the cinnamic series of general formula (I): The invention also relates to the process for preparing said guanidine derivatives and also to synthetic intermediates. Finally, the invention relates to t