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329-71-5

329-71-5

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329-71-5 Usage

Chemical Properties

Yellow needles, flammable. Soluble in ether, benzene, hot water, and ethanol.

General Description

Yellow crystalline solid with a sweet musty odor. Sinks and mixes slowly with water.

Air & Water Reactions

Slowly mixes with water.

Reactivity Profile

2,5-DINITROPHENOL can detonate or explode when heated under confinement [USCG, 1999]. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases.

Health Hazard

INHALATION, INGESTION OR SKIN ABSORPTION: Fatigue, thirst, sweating, flushing of face, nausea, vomiting, abdominal pain, diarrhea; restlessness, anxiety, excitement occasionaly leading to convulsions; fever, tachycardia, labored respiration, cyanosis, and sometimes muscle cramps. Loss of consciousness, cessation of breathing and death. EYES: Causes dilation of pupils or posterior subcapsular opacities or cataracts. SKIN: Discoloration, irritation, and dermatitis.

Purification Methods

Crystallise 2,5-dinitrophenol from H2O with a little EtOH. [Beilstein 6 IV 1383.]

Check Digit Verification of cas no

The CAS Registry Mumber 329-71-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,2 and 9 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 329-71:
(5*3)+(4*2)+(3*9)+(2*7)+(1*1)=65
65 % 10 = 5
So 329-71-5 is a valid CAS Registry Number.
InChI:InChI=1/C6H4N2O5/c9-6-3-4(7(10)11)1-2-5(6)8(12)13/h1-3,9H

329-71-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,5-dinitrophenol

1.2 Other means of identification

Product number -
Other names 2,5-DINITROPHENOL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:329-71-5 SDS

329-71-5Relevant articles and documents

Reactivity of α-amino acids in the N-acylation with benzoic acid esters in aqueous dioxane

Ishkulova,Oparina,Kochetova,Kustova,Kalinina,Kuritsin

experimental part, p. 964 - 967 (2011/01/07)

The effect of the nitro group as a substituent in the phenoxide part of phenyl benzoate on the rate of N-acylation of glycine, L-proline,and L-valine in the water (40 wt %)-dioxane solvent was studied. The activation parameters of glycine reactions with the esters were measured. The existence of compensation effect and the linear relation of the logarithms of the acylation constants to the Hammett constants were revealed. The energy of the LUMO of esters can serve as the descriptors of the easters reactivity. Pleiades Publishing, Ltd., 2010.

Associative and Dissociative Pathways in the Alkaline Hydrolysis of Aryl 2-Hydroxycinnamates

Cevasco, Giorgio,Thea, Sergio

, p. 70 - 73 (2007/10/02)

Aryl 2-hydroxycinnamate esters hydrolyze in alkaline solutions (20percent dioxane-water v/v) obeying the rate law kobs = ka + kb/(1 + aH/Ka), where Ka is the ionization constant of the hydroxy group of the ester and kb is the second-order rate constant for the attack of hydroxide ion on the ionized ester.Kinetic data and activation parameters for the hydrolysis of the 2,4-dinitrophenyl ester show that the mechanism giving rise to the ka term cannot be a simple BAc2 type process and suggest the occurrence of a E1cB mechanism involving an "extended" o-oxoketene intermediate.The Broensted plot of the apparent second-order rate constante (kaKa/kw) versus the pK of the leaving group indicates that the reaction mechanism changes from E1cB to BAc2 for esters with leaving groups having pK higher than about 6.

Synthese von Di- und Tri(o-phenylendiamin)-Liganden

Hahn, Ekkehardt F.,Dittler-Klingemann, Andreas

, p. 779 - 782 (2007/10/02)

The o-phenylenediamine ligand trisamine, TRIPACEN (4) and bisamine, DIPACEN (8) are obtained by Williamson coupling of the potassium salt of 2,3-dinitrophenole (1) to tris(3-chlorpropyl)amine (2) or benzylbis(3-chlorpropyl)amine (5), respectively, followed by reduction of the nitro functions with Sn/HCl or Pd(OH)2/H2.