Synthesis and structural Characterization of 12, an Unusual Example of a 'Paddle-Wheel' Dodecametallic Thiolate Cluster

DOI: 10.1039/c39880001031

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1031 - 1033 (1988)

Update date:2022-08-11

Topics:

Authors:

Block, Eric

Gernon, Michael

Kang, Hyunkyu

Liu, Shuncheng

Zubieta, Jon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880001031

Treatment of PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC6H4-o-SiMe3, affords red-orange crystals of 12, a dodecametallic thiolate cluster with a "paddle-wheel' C12S12 core.

Full text of DOI:10.1039/c39880001031

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzenethiol, 2-(trimethylsilyl)-

Cas No:33356-45-5

R&D Labs maybe for 33356-45-5

Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Beijing Mashi Fine Chemical Co.,Ltd.

Contact:+86-10-61271592

Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China

Relevant to this article

PURIFICATION AND PROPERTIES OF CAFFEIC ACID O-METHYLTRANSFERASE FROM ALFALFA ROOT NODULES

Doi:10.1016/0031-9422(81)85215-6
(1981)
SITE OF PROTONATION AND CONFORMATIONAL EFFECTS ON GAS-PHASE BASICITY IN beta -AMINO ALCOHOLS. THE NATURE OF INTERNAL H BONDING IN beta -HYDROXY AMMONIUM IONS.

Doi:10.1021/ja00349a006
(1983)
Mercuric nitrate-mediated deprotection of oximes, hydrazones, and semicarbazones

Doi:10.1081/SCC-120038512
(2004)
Solid-state thin film cell for in situ transmission electron microscopy of electrodeposited silver on gold

Doi:10.1149/1.2097263
(1989)
Distinguishing Rate-Limiting Electron versus H-Atom Transfers in Cu ₂(O₂)-Mediated Oxidative N-Dealkylations: Application of Inter- versus Intramolecular Kinetic Isotope Effects

Doi:10.1021/ja0359409
(2003)
Doi:10.1039/P29770000125
(1977)

Article Doi