Synthesis and structural Characterization of 12, an Unusual Example of a 'Paddle-Wheel' Dodecametallic Thiolate Cluster

DOI: 10.1039/c39880001031

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1031 - 1033 (1988)

Update date:2022-08-11

Topics:

Authors:

Block, Eric

Gernon, Michael

Kang, Hyunkyu

Liu, Shuncheng

Zubieta, Jon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880001031

Treatment of PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC6H4-o-SiMe3, affords red-orange crystals of 12, a dodecametallic thiolate cluster with a "paddle-wheel' C12S12 core.

Full text of DOI:10.1039/c39880001031

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzenethiol, 2-(trimethylsilyl)-

Cas No:33356-45-5

R&D Labs maybe for 33356-45-5

Shanghai PurityPE Biotechnology Co., Ltd.

website:http://www.puritype.com

Contact:+86-18917347808; +86-15921887593

Address:Room 907, Tongda Venture Building, No.1, Lane 600, Tianshan Road, Shanghai, China
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Oren Hydrocarbons (Qingdao) Co., Ltd.

Contact:+86-532-68607667-801

Address:Room 3 # 302, No.9 Qingyun Road, Qingdao, China
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu

Relevant to this article

PURIFICATION AND PROPERTIES OF CAFFEIC ACID O-METHYLTRANSFERASE FROM ALFALFA ROOT NODULES

Doi:10.1016/0031-9422(81)85215-6
(1981)
SITE OF PROTONATION AND CONFORMATIONAL EFFECTS ON GAS-PHASE BASICITY IN beta -AMINO ALCOHOLS. THE NATURE OF INTERNAL H BONDING IN beta -HYDROXY AMMONIUM IONS.

Doi:10.1021/ja00349a006
(1983)
Mercuric nitrate-mediated deprotection of oximes, hydrazones, and semicarbazones

Doi:10.1081/SCC-120038512
(2004)
Solid-state thin film cell for in situ transmission electron microscopy of electrodeposited silver on gold

Doi:10.1149/1.2097263
(1989)
Distinguishing Rate-Limiting Electron versus H-Atom Transfers in Cu ₂(O₂)-Mediated Oxidative N-Dealkylations: Application of Inter- versus Intramolecular Kinetic Isotope Effects

Doi:10.1021/ja0359409
(2003)
Doi:10.1039/P29770000125
(1977)

Article Doi