Synthesis and structural Characterization of 12, an Unusual Example of a 'Paddle-Wheel' Dodecametallic Thiolate Cluster

DOI: 10.1039/c39880001031

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1031 - 1033 (1988)

Update date:2022-08-11

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Authors:

Block, Eric

Gernon, Michael

Kang, Hyunkyu

Liu, Shuncheng

Zubieta, Jon

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Article abstract of DOI:10.1039/c39880001031

Treatment of PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC6H4-o-SiMe3, affords red-orange crystals of 12, a dodecametallic thiolate cluster with a "paddle-wheel' C12S12 core.

Full text of DOI:10.1039/c39880001031

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