335-01-3Relevant articles and documents
Sullivan et al.
, p. 2611 (1970)
A NEW SYNTHESIS OF DIFLUORAMINO TRIFLUOROMETHANE
Schack, Carl J.
, p. 583 - 586 (1981)
Fluorination of azidotrifluoromethane furnishes difluoramino trifluoromethane in a direct, reproducible, and high yield reaction.A maximum rate of conversion with minimum degradation was obtained at 70-80 deg.Enhancement of the rate of reaction was realized with added KF as a catalyst.
On the reaction of perfluoro-aza-propene with oxygen difluoride and fluorination of bis(trifluoromethyl)-hydroxylamine
Minkwitz, Rolf,Reinemann, Stefan,Ludwig, Ralf
, p. 145 - 149 (2007/10/03)
The reactions of perfluoro-aza-propene CF3NCF2 with an excess of oxygen difluoride OF2 and the fluorination of bis(trifluoromethyl)-hydroxylamine (CF3)2NOH are discussed. Additionally, we present density functional calculations (B3LYP/6-31G*) on bis(trifluoromethyl)-hypofluorite (CF3)2NOF, which clearly show that this molecule is a model substance for the discussion of negative hyperconjugation.