33804-84-1

Basic information

• Product Name: 2-methyl-2H-isoindole
• Synonyms: 2H-isoindole, 2-methyl-; 2-Methyl-2H-isoindole; 2-Methylisoindole
• CAS NO: 33804-84-1
• Molecular Formula: C₉H₉N
• Molecular Weight: 131.1745
• Mol File: 33804-84-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 241.4°C at 760 mmHg
• Flash Point: 99.8°C
• Density: 1g/cm³
• Vapor Pressure: 0.0558mmHg at 25°C
• Refractive Index: 1.57
• CAS DataBase Reference: 2-methyl-2H-isoindole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-2H-isoindole(33804-84-1)
• EPA Substance Registry System: 2-methyl-2H-isoindole(33804-84-1)

Safety Data

• Hazardous Substances Data: 33804-84-1(Hazardous Substances Data)

Upstream product

• 7664-41-7 ammonia 
• 16840-49-6 2-methyl-2-phenyl-isoindolinium; iodide 
• 142-96-1 dibutyl ether 
• 59998-15-1 2-benzyl-2-methyl-isoindolinium; bromide 
• 591-51-5 phenyllithium 
• 550-44-7 N-methylphthalimide 
• 141-52-6 sodium ethanolate 

Downstream Products

• 1446186-34-0 2-bromo-9-methyl-3-phenyl-1,4-dihydro-1,4-epiminonaphthalene 
• 1446186-35-1 2-bromo-3-hexyl-9-methyl-1,4-dihydro-1,4-epiminonaphthalene 
• 1446186-36-2 2-bromo-3-(tert-butyl)-9-methyl-1,4-dihydro-1,4-epiminonaphthalene 
• 1446186-40-8 2-methyl-1-(phenylethynyl)-3-[(triisopropylsilyl)ethynyl]-2H-isoindole 
• 1446186-56-6 2-methyl-1,3-bis(phenylethynyl)-2H-isoindole 
• 1446186-57-7 2-methyl-1,3-bis(p-tolylethynyl)-2H-isoindole 
• 1446186-58-8 1,1'-(((2-methyl-2H-isoindole-1,3-diyl)bis(ethyne-2,1-diyl))bis(4,1-phenylene))diethanone 
• 4276-24-8 1,3-diphenyl-2-methylisoindole 
• 1265964-79-1 5,12-dihydro-13-methyl-5,12-diphenylnaphthacene-5,12-imine 
• 89708-18-9 C₁₉H₁₆N₂O₂ 
• 89647-39-2 C₁₉H₁₆N₂O₂ 
• 3474-87-1 2-methylisoindoline 
• 39698-71-0 14,14-dimethyl-(5at,11at)-5,5a,6,11,11a,12-hexahydro-6t,11t-epiazano-5r,12c-epioxido-naphthacenium; tetraphenylborate^(1-) 

Relevant articles and documents

Mild and selective Et2Zn-catalyzed reduction of tertiary amides under Hydrosilylation conditions

Diethylzinc (Et2Zn) can be used as an efficient and chemoselective catalyst for the reduction of tertiary amides under mild reaction conditions employing cost-effective polymeric silane (PMHS) as the hydride source. Crucial for the catalytic activity was the addition of a substoichiometric amount of lithium chloride to the reaction mixture. A series of amides containing different additional functional groups were reduced to their corresponding amines, and the products were isolated in good-to-excellent yields.