13125-70-7

Upstream product

• 33877-11-1 1-Phenylethanethiol 
• 74-93-1 methylthiol 
• 585-71-7 (1-bromoethyl)benzne 
• 100-53-8 phenylmethanethiol 
• 74-88-4 methyl iodide 
• 100-42-5 styrene 
• 624-92-0 Dimethyldisulphide 
• 1669-98-3 Ethyl methyl sulfoxide 
• 555-54-4 diphenylmagnesium 
• 591-51-5 phenyllithium 
• 150-60-7 dibenzyl disulphide 
• 766-92-7 [(methylthio)methyl]-benzene 
• 52791-97-6 lithium phenylmethanethiolate 
• 98-85-1 1-Phenylethanol 

Downstream Products

• 4843-35-0 1-Methylmercapto-1-phenyl-2-phenylmercapto-ethylen 
• 116999-34-9 dimethyl(1-phenylethyl)sulfonium iodide 
• 100-42-5 styrene 
• 1077-16-3 hexylbenzene 
• 52053-61-9 di(α-methylbenzyl)disulfide 
• 94265-89-1 bis(1-methyl-1-phenylethyl)disulfide 
• 6031-02-3 2-phenylhexane 
• 71521-89-6 1-butyl-2-hexylbenzene 
• 24531-98-4 (+/-)-dimethyl-(1-phenyl-ethyl)-sulfonium ; bromide 
• 28147-27-5 methyl-(1-phenyl-ethyl)-sulfone 

Relevant academic research and scientific papers

Hemin-Catalyzed Addition Reactions of Thiophenols to Styrene

Hemin promotes the Markovnikov-type addition reactions of thiols (origins of the thiols are their disulfide derivatives) to styrene in benzene-ethanol (1:1) containing NaBH4.The plausible reaction mechanism has been discussed.

Kinetic resolution of secondary alcohols using proline-derived bicyclic iminium salts

The proline-derived bicyclic iminium salt 3 can be used to bring about kinetic resolution in its reaction with salts of secondary alcohols to give the corresponding methyl sulfides. Reaction proceeds most efficiently with sodium 1-phenylethoxide in toluene at RT where either 3 or the benzyl salt 14 give e.e.s of 21-25% and changing the heteroatoms present in the sails, the metal cation used and the solvent and temperature all give similar or lower selectivity.

A MILD AND EFFICIENT SYNTHESIS OF THIOLESTERS FROM ALCOHOLS

Nomerous functionally diverse thiolesters are prepared in high yield in a mild "one-pot" synthesis from activated alcohols and thiolacids under Lewis acid catalysis.

Metalation reactions. VIII. Metalation of benzyl methyl sulfide

The metalation of benzylmethyl sulfide with n-butyllithium in hexane and in the presence of TMEDA has been investigated.The results show that metalation occurs only at the benzylic position with no wittig type rearrangement, cleavage of thioether bond and

The Formation of 1,2-Bis(alkylthio)-1,2-diphenylethanes by the Lithium Diisopropylamide-induced Fragmentation of Dibenzyl Disulfide Followed by the Trapping with Some Alkyl Halides

It was found that dibenzyl disulfide undergoes lithium diisopropylamide-induced fragmentation to afford several intermediate species which, on trapping with alkyl halides, lead to the formation of 1,2-bis(alkylthio)-1,2-diphenylethanes and α-alkylbenzyl alkyl sulfides.