13125-70-7

Basic information

• Product Name: Benzene, [1-(methylthio)ethyl]-
• CAS NO: 13125-70-7
• Molecular Formula: C9H12S
• Molecular Weight: 152.26
• Mol File: 13125-70-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, [1-(methylthio)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1-(methylthio)ethyl]-(13125-70-7)
• EPA Substance Registry System: Benzene, [1-(methylthio)ethyl]-(13125-70-7)

Safety Data

• Hazardous Substances Data: 13125-70-7(Hazardous Substances Data)

Upstream product

• 74-93-1 methylthiol 
• 585-71-7 (1-bromoethyl)benzne 
• 1669-98-3 Ethyl methyl sulfoxide 
• 591-51-5 phenyllithium 
• 150-60-7 dibenzyl disulphide 
• 74-88-4 methyl iodide 
• 766-92-7 [(methylthio)methyl]-benzene 
• 52791-97-6 lithium phenylmethanethiolate 
• 672-65-1 (1-chloroethyl)benzene 
• 1004-09-7 (rac)-sodium 1-phenylethanolate 
• 98-85-1 1-Phenylethanol 
• 555-54-4 diphenylmagnesium 
• 100-42-5 styrene 
• 624-92-0 Dimethyldisulphide 

Downstream Products

• 100-42-5 styrene 
• 6031-02-3 2-phenylhexane 
• 52053-61-9 di(α-methylbenzyl)disulfide 
• 94265-89-1 bis(1-methyl-1-phenylethyl)disulfide 
• 71521-89-6 1-butyl-2-hexylbenzene 
• 1077-16-3 hexylbenzene 
• 116999-34-9 dimethyl(1-phenylethyl)sulfonium iodide 
• 4843-35-0 1-Methylmercapto-1-phenyl-2-phenylmercapto-ethylen 
• 24531-98-4 (+/-)-dimethyl-(1-phenyl-ethyl)-sulfonium ; bromide 
• 28147-27-5 methyl-(1-phenyl-ethyl)-sulfone 

Relevant articles and documents

Hemin-Catalyzed Addition Reactions of Thiophenols to Styrene

Hemin promotes the Markovnikov-type addition reactions of thiols (origins of the thiols are their disulfide derivatives) to styrene in benzene-ethanol (1:1) containing NaBH4.The plausible reaction mechanism has been discussed.

A MILD AND EFFICIENT SYNTHESIS OF THIOLESTERS FROM ALCOHOLS

Nomerous functionally diverse thiolesters are prepared in high yield in a mild "one-pot" synthesis from activated alcohols and thiolacids under Lewis acid catalysis.

The Formation of 1,2-Bis(alkylthio)-1,2-diphenylethanes by the Lithium Diisopropylamide-induced Fragmentation of Dibenzyl Disulfide Followed by the Trapping with Some Alkyl Halides

It was found that dibenzyl disulfide undergoes lithium diisopropylamide-induced fragmentation to afford several intermediate species which, on trapping with alkyl halides, lead to the formation of 1,2-bis(alkylthio)-1,2-diphenylethanes and α-alkylbenzyl alkyl sulfides.