3395-76-4

Upstream product

• 26254-04-6 N,N'-dibenzyl-hydrazine; hydrochloride 
• 7626-68-8 N,N'-dibenzylhydrazine 
• 100-46-9 benzylamine 
• 7664-41-7 ammonia 
• 7732-18-5 water 
• 7722-84-1 dihydrogen peroxide 
• 7705-08-0 iron(III) chloride 

Downstream Products

• 13211-11-5 benzaldehyde benzylhydrazone 
• 588-59-0 stilbene 
• 806-69-9 1,2,3,4-tetraphenylbutane 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 108-88-3 toluene 
• 124116-92-3 1,2-dibenzyl-4,4-diphenyl-[1,2]diazetidin-3-one 
• 2154-56-5 benzyl radical 
• 7626-68-8 N,N'-dibenzylhydrazine 
• 78075-59-9 4-benzyl-1-naphthalenecarbonitrile 
• 2362-50-7 thianthrene-5-oxide 
• 588-46-5 N-(phenylmethyl)acetamide 
• 104936-67-6 1-benzyl-5-methyl-3-phenyl-1H-1,2,4-triazole 
• 10264-12-7 N-benzylpropanamide 
• 104936-68-7 1-Benzyl-5-ethyl-3-phenyl-1H-[1,2,4]triazole 

Relevant academic research and scientific papers

Improved Process for Preparing Alicyclic Diamine

The present invention relates to a method for synthesizing an alicyclic diamine compound. Provided is a method for producing bicyclohexanediamines in a higher yield while inhibiting production of an aromatic byproduct.COPYRIGHT KIPO 2018

Selective N-oxidation of aromatic amines to nitroso derivatives using a molybdenum acetylide oxo-peroxo complex as catalyst

The molybdenum acetylide oxo-peroxo complex obtained in situ by the treatment of the corresponding molybdenum acetylide carbonyl complex, CpMo(CO)3(C{triple bond, long}CPh); Cp = η5-C5H5 with H2O2, has been used as an efficient catalyst for selective N-oxidation of primary amines to nitroso derivatives. Excellent amine conversion (up to 100%) and very high selectivity for nitroso compounds (99%) have been obtained using 30% hydrogen peroxide as an oxidant. The oxo peroxo Mo(VI) complex has also been found to be very active for the oxidation of various substituted primary aromatic amines with electron donating as well as electron withdrawing substituents on the aromatic ring.

NOVEL OXIDATION OF 1,2-DIBENZYLHYDRAZINES WITH CARBON TETRACHLORIDE

1,2-Dibenzylhydrazines are cleanly oxidized to the corresponding ω,ω'-azotoluenes by carbon tetrachloride; carried out under phase-transfer conditions in the presence of sodium carbonate, the new reaction provides a clean, inexpensive, nearly quantitative route to the azotoluenes.