3408-13-7

Basic information

• Product Name: [2,2'-Binaphthalene]-1,1',4,4'-tetrone
• CAS NO: 3408-13-7
• Molecular Formula: C20H10O4
• Molecular Weight: 314.297
• Mol File: 3408-13-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: [2,2'-Binaphthalene]-1,1',4,4'-tetrone(CAS DataBase Reference)
• NIST Chemistry Reference: [2,2'-Binaphthalene]-1,1',4,4'-tetrone(3408-13-7)
• EPA Substance Registry System: [2,2'-Binaphthalene]-1,1',4,4'-tetrone(3408-13-7)

Safety Data

• Hazardous Substances Data: 3408-13-7(Hazardous Substances Data)

Usage

General Description

[2,2'-Binaphthalene]-1,1',4,4'-tetrone is a chemical compound with the molecular formula C20H10O4. It is a tetraketone derivative of [2,2'-binaphthalene], which is a classic chiral ligand in asymmetric synthesis. The compound has a tetracyclic structure containing two naphthalene rings connected by a central four-carbonyl group. The compound has been studied for its potential applications in organic synthesis and as a building block for the synthesis of other biologically active compounds. Additionally, it has been investigated for its potential use in the development of new materials and pharmaceuticals due to its unique structure and reactivity.

Upstream product

• 130-15-4 [1,4]naphthoquinone 
• 84-85-5 4-methoxynaphth-1-ol 
• 1191-99-7 2,3-dihydro-2H-furan 
• 5959-56-8 4-amino-1-naphthol hydrochloride 

Downstream Products

• 612-78-2 2,2'-binaphthalene 
• 33440-64-1 2,2'-bis(3-hydroxy-1,4-naphthoquinone) 
• 26171-90-4 Dinaphtho<2,3-b;2',3'-d>furan-5,13;7,12-dichinon 
• 107727-89-9 5,7,12-triacetoxy-13-phenyldibenzocarbazole 
• 107727-88-8 5-acetoxy-13-phenyldibenzocarbazole-7,12-quinone 
• 74066-60-7 5-hydroxydinaphtho<1,2-b:2',3'-d>furan-7,12-quinone 
• 111061-32-6 2,2'-binaphthyl-1,1',4,4'-tetrol 
• 6880-74-6 Hepta<2.2.2>starphen-5,18:6,11:12,17-trichinon 
• 21418-12-2 1,4,1',4'-Tetraacetoxy-[2,2']binaphthyl 
• 5697-00-7 1,4-diacetoxynaphthalene 

Relevant articles and documents

Anodic oxidation of 4-methoxy-1-naphthol

Anodic oxidation of 4-methoxy-1-naphthol 1 in the presence of nucleophiles provided the corresponding products 8-12 and the dimers 13 and 17 were also produced. The reaction mechanism of the oxidation reaction including the [3+2] cycloaddition was investigated.

A facile synthesis of naturally occurring binaphthoquinones: Efficient oxidative dimerization of 4-alkoxy-1-naphthols using silver(II) oxide-40% nitric acid

Oxidation of 4-alkoxy-1-naphthols with AgO-40% HNO3 occurred along with a dimerization to give the corresponding bi-1,4-naphthoquinones. The oxidative dimerization required one hydroxyl group and took place at its ortho position. This reaction was applicable to syntheses of naturally occurring binaphthoquinones, bivitamin K3 and 3,3′-bijuglone.