34304-79-5Relevant academic research and scientific papers
Ethylbenzene oxidation in the presence of acetic anhydride
Nosacheva,Revkov,Perkel
, p. 443 - 447 (2008/02/02)
The kinetics of formation and subsequent transformation of the products of ethylbenzene oxidation in the presence of acetic anhydride at 100°C was studied by solution of the inverse kinetic problem.
Chemiluminescence of secondary peroxyesters
Dixon, Brian G.,Schuster, Gary B.
, p. 3068 - 3077 (2007/10/02)
The thermolysis of 1-phenylethyl peroxyacetate and a series of substituted 1-phenylethyl peroxybenzoates was investigated. Thermolysis in benzene gives acetophenone and the corresponding carboxylic acid. The study of the reaction kinetics and kinetic isotope effect indicates that the unimolecular thermolysis proceeds by homolysis of the oxygen-oxygen bond. Electronically excited states are formed in the thermolyses of these peroxyesters. These are detected by their characteristic direct chemiluminescence or by indirect chemiluminescence. In the presence of easily oxidized catalysts these peroxyesters give excited states by the chemically initiated electron-exchange luminescence (CIEEL) path. The mechanism of these luminescent reactions was investigated.
