3487-90-9

Basic information

• Product Name: 2-Propenoic acid, 3-(2-hydroxyphenyl)-, butyl ester, (2E)-
• CAS NO: 3487-90-9
• Molecular Formula: C13H16O3
• Molecular Weight: 220.268
• Mol File: 3487-90-9.mol

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(2-hydroxyphenyl)-, butyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(2-hydroxyphenyl)-, butyl ester, (2E)-(3487-90-9)
• EPA Substance Registry System: 2-Propenoic acid, 3-(2-hydroxyphenyl)-, butyl ester, (2E)-(3487-90-9)

Safety Data

• Hazardous Substances Data: 3487-90-9(Hazardous Substances Data)

Upstream product

• 141-32-2 acrylic acid n-butyl ester 
• 95-56-7 2-hydroxybromobenzene 
• 533-58-4 2-Iodophenol 
• 90-02-8 salicylaldehyde 
• 98-80-6 phenylboronic acid 
• 64908-64-1 2-phenoxyisoindol-1,3-dione 
• 4846-21-3 O-phenylhydroxylamine 

Downstream Products

• 170456-76-5 4-(4-methoxyphenyl)coumarin 
• 864354-17-6 4-([1,1'-biphenyl]-4-yl)-2H-chromen-2-one 
• 864354-16-5 4-(2-oxo-2H-chromen-4-yl)-benzaldehyde 
• 852171-80-3 4-(4-tert-butylphenyl)-2H-benzopyran-2-one 
• 91-64-5 coumarin 

Relevant articles and documents

Rh-Catalyzed Deformylative Coupling of Salicylaldehydes with Acrylates and Acrylamides

An unprecedented deformylative coupling of salicylaldehydes to acrylates and acrylamides under Rh-catalyzed conditions is reported. These deformylative couplings afforded o-hydroxycinnamates and o-hydroxycinnamamides with broad functional group tolerance and high chemoselectivity under milder reaction conditions.

Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes

Herein, we report an unprecedented regioselective and entirely atom-economic cobalt(III)-catalyzed method for the non-annulative, intermolecular carboamination of alkenes. The methodology enables the direct synthesis of unnatural amino acid derivatives an

Ligand-free copper-catalyzed arylation of olefins by the mizoroki-heck reaction

A novel ligand-free copper-catalyzed Mizoroki-Heck cross-coupling reaction of various aryl iodides with olefins has been developed. Both the solvent and the base were found to have a fundamental influence on the efficiency of the transformation in the presence of 10 mol% Cu, with DMF and tetramethylammonium bromide (TMAB) being the optimal solvent and base, respectively. As a result, a set of the corresponding E-internal olefins were obtained selectively in moderate to good yields.

Highly efficient, recyclable Pd(II) catalysts with bisimidazole ligands for the heck reaction in ionic liquids

(Matrix presented) New Pd(II) complexes with bisimidazole ligands were prepared and proved to be effective catalysts for the Heck reaction under phosphine-free conditions using ionic liquids as solvents. This system could be recycled five times without any loss of catalytic activity.

Palladium/tetraphosphine catalysed Heck reaction with ortho-substituted aryl bromides

The tetraphosphine cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane associated to [PdCl(C3H5)]2 catalyses the Heck reaction of butyl acrylate with a wide range of sterically demanding aryl bromides, furnis