34880-70-1

Basic information

• Product Name: 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE
• Synonyms: 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE;[(1-METHOXY-1-PROPENYL)OXY]TRIMETHYLSILANE;Methoxytrimethylsilyloxypropene;1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE 95+%;1-(Trimethylsiloxy)-1-methoxy-1-propene;Methylketene methyl(trimethylsilyl)acetal;Trimethyl(1-methoxy-1-propenyloxy)silane;(E)-((1-Methoxyprop-1-en-1-yl)oxy)triMethylsilane
• CAS NO: 34880-70-1
• Molecular Formula: C₇H₁₆O₂Si
• Molecular Weight: 160.29
• Product Categories: Monoalkoxysilanes;Protection & Derivatization Reagents (for Synthesis);Si (Classes of Silicon Compounds);Si-O Compounds;Synthetic Organic Chemistry;Vinylsilanes, Allylsilanes
• Mol File: 34880-70-1.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 52 °C / 27mmHg
• Flash Point: 23.505°C
• Appearance: /
• Density: 0.87
• Vapor Pressure: 9.805mmHg at 25°C
• Refractive Index: 1.4130-1.4160
• Storage Temp.: 0-10°C
• CAS DataBase Reference: 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE(34880-70-1)
• EPA Substance Registry System: 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE(34880-70-1)

Safety Data

• RIDADR: 1993
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 34880-70-1(Hazardous Substances Data)

Usage

General Description

1-Methoxy-1-trimethylsilyloxypropene is a chemical compound that consists of a propene backbone with a methoxy (-OCH3) and a trimethylsilyloxy (-OSi(CH3)3) group attached to the same carbon atom. It is commonly used as a building block in organic synthesis and as a reagent in various chemical reactions. 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE is often employed in the preparation of a wide range of organic molecules, including pharmaceuticals, agrochemicals, and materials. It is a versatile intermediate that can undergo various transformations to yield different organic products. Additionally, 1-methoxy-1-trimethylsilyloxypropene is considered to be relatively stable, making it a valuable component in the field of organic chemistry.

InChI:InChI=1/C7H16O2Si/c1-6-7(8-2)9-10(3,4)5/h6H,1-5H3/b7-6+

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 554-12-1 propanoic acid methyl ester 

Downstream Products

• 113107-60-1 dimethyl 2,5-dimethyl-3-(phenylthio)adipate 
• 75436-64-5 7aβ-hydroxy-3,3aβ-dimethylhexahydrobenzofuran-2(3H)-one 
• 75436-63-4 methyl 2-(1-methyl-2-oxocyclohexyl)propionate 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 17324-17-3 trans-3-methyl-1,4-diphenylazetidin-2-one 
• 22628-31-5 syn-3-methyl-1,4-diphenylazetidin-2-one 
• 24948-31-0 syn-methyl 2-methyl-3-phenyl-3-(phenylamino)propanoate 
• 24948-31-0 (2S,3R)-2-Methyl-3-phenyl-3-phenylamino-propionic acid methyl ester 
• 57956-45-3 Methyl 2-Methyl-3-phenyl-3-(trimethylsiloxy)propionate 
• 23210-22-2 1-Phenyl-3-methylindolin-2-one 
• 122-39-4 diphenylamine 
• 21673-18-7 methyl 2-(phenylthio)propanoate 
• 50460-80-5 dimethyl 2-hydroxy-3-methylbutane-1,4-dioate 
• 50460-80-5 dimethyl 2-hydroxy-3-methylbutane-1,4-dioate 

Relevant articles and documents

Synthesis and isolation of α-oxo sulfines

The synthesis of several α-oxo sulfines is discribed. Various α-oxo sulfines can be isolated as such. The Diels-Alder reaction of these sulfines with 1,3-dienes can be catalyzed by Lewis acids.

Regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals

(Equation Presented). The regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals was accomplished. Various alkenes such as ethylene, 1-alkenes, and cyclic alkenes were applicable for this reaction system. The alkyli

Surface-mediated solid phase reaction. Part 9. A convenient procedure for aldol reaction of ketene silyl acetals with aldehydes on the solid surface of alumina

The aldol reaction of ketene silyl acetals with aldehydes proceeds efficiently on the solid surface of alumina impregnated with anhydrous zinc chloride under sonication providing aldol products in high yields and with good stereoselectivity.