349545-05-7

Basic information

• Product Name: (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂
• Synonyms: (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂
• CAS NO: 349545-05-7
• Molecular Weight: 558.287
• Mol File: 349545-05-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂(349545-05-7)
• EPA Substance Registry System: (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂(349545-05-7)

Safety Data

• Hazardous Substances Data: 349545-05-7(Hazardous Substances Data)

Upstream product

• 317322-17-1 [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] 
• 7784-34-1 arsenic trichloride 
• 402824-10-6 Li(2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)(tetrahydtofuran) 
• 13450-90-3 Gallium trichloride 
• 334719-92-5 Dipp₂nacnacLi*Et₂O 

Downstream Products

• 381225-69-0 (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl(OSO₂CF₃) 
• 1227501-99-6 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(OEt)2 
• 1227502-00-2 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(OEt)Cl 
• 850131-83-8 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(OH)2 
• 1227501-92-9 [HC{C(Me)N(2,6-iPr₂C₆H₃)}₂]Ga(NHEt)₂ 
• 1227501-97-4 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(NHEt)Cl 
• 1227501-93-0 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(NHiPr)2 
• 1227501-95-2 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(NHPh)2 
• 1227501-94-1 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(NHnBu)2 
• 1227501-96-3 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(NHtBu)Cl 
• 850131-82-7 [(CH(C(CH₃)N(C₆H₃(CH(CH₃)2)2))2)Ga(NH₂)2] 

Relevant articles and documents

Synthesis and structures of gallaarsenes LGaAsGa(X)L featuring a Ga-As double bond

Three equivalents of LGa {L = HC[C(Me)N(2,6-i-Pr2C6H3)]2} react with AsX3 (X = Cl, Br) by insertion into two As-X bonds, followed by the elimination of LGaX2 and formation of LGaAsGa(Cl)L (1) and LGaAsGa(Br)L (2). According to single crystal X-ray analysis, 1 and 2 each exhibit one Ga-As single bond and one Ga-As double bond. The π-bonding contribution (9.71 kcal mol-11 and 9.44 kcal mol-12) was proved by variable temperature (VT) 1H NMR spectroscopy, while the electronic structure of 1′ was studied by quantum chemical calculations.

Formation and Cleavage of a Sb?Sb Double Bond: From Carbene-Coordinated Distibenes to Stibinidenes

Reactions of L(Cl)Ga-substituted stibine [L(Cl)Ga]2SbCl (L=HC[C(Me)NAr]2; Ar=2,6-i-Pr2C6H3) with N-heterocyclic carbenes RNHCMe (RNHCMe=[C(R)NMe]2C:; R=Me, Et, iPr) gave NHC-coordinated stibinidenes L(Cl)GaSb-RNHCMe (R=Me 1 a, Et 1 b, iPr 1 c) and distibenes L(Cl)GaSbSb(RNHCMe)Ga(Cl)L (R=Me 2 a, Et 2 b, iPr 2 c). Distibenes 2 a and 2 b react with a second equivalent of RNHCMe with cleavage of the Sb?Sb double bond and formation of stibinidenes 1 a and 1 b. 1 a–2 b were spectroscopically characterized and the solid-state structures determined by single crystal X-ray diffraction (sc-XRD). Quantum chemical calculations gave a deeper insight into the electronic nature and bonding situation of 1 a–2 c and the reaction energetics were investigated in detail.

Siloxide and triflate gallium(III) complexes supported by the BDI Ligand

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