3508-77-8

Basic information

• Product Name: ethyl 2-acetyl-2-allylpent-4-ene-1-oate
• Synonyms: ethyl 2-acetyl-2-allylpent-4-ene-1-oate;2-Acetyl-2-(2-propenyl)-4-pentenoic acid ethyl ester;2-Acetyl-2-allyl-4-pentenoic acid ethyl ester;4-Pentenoic acid, 2-acetyl-2-(2-propenyl)-, ethyl ester;Ai3-30529;Einecs 222-508-3
• CAS NO: 3508-77-8
• Molecular Formula: C₁₂H₁₈O₃
• Molecular Weight: 210.26952
• EINECS: 222-508-3
• Mol File: 3508-77-8.mol
• Article Data: 43

Chemical Properties

• Boiling Point: 265.7°Cat760mmHg
• Flash Point: 109.1°C
• Appearance: /
• Density: 0.966g/cm³
• Vapor Pressure: 0.00904mmHg at 25°C
• Refractive Index: 1.453
• CAS DataBase Reference: ethyl 2-acetyl-2-allylpent-4-ene-1-oate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-acetyl-2-allylpent-4-ene-1-oate(3508-77-8)
• EPA Substance Registry System: ethyl 2-acetyl-2-allylpent-4-ene-1-oate(3508-77-8)

Safety Data

• Hazardous Substances Data: 3508-77-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H18O3/c1-5-8-12(9-6-2,10(4)13)11(14)15-7-3/h5-6H,1-2,7-9H2,3-4H3

Upstream product

• 141-97-9 ethyl acetoacetate 
• 107-05-1 3-chloroprop-1-ene 
• 66279-50-3 ethylacetoacetate, K(+) salt 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 
• 556-56-9 allyl iodid 
• 591-87-7 Allyl acetate 
• 610-89-9 2-acetyl-pent-4-enoic acid ethyl ester 
• 107-18-6 allyl alcohol 
• 1469-70-1 allyl ethyl carbonate 
• 85021-16-5 allyl N-phenyliminobenzoate 
• 17686-63-4 acetone O-<(allyloxy)-carbonyl>oxime 
• 35466-83-2 allyl methyl carbonate 
• 1693-71-6 tris(allyl)borate 

Downstream Products

• 54385-33-0 methyl 2-(prop-2-enyl)pent-4-enoate 
• 64-19-7 acetic acid 
• 610-89-9 2-acetyl-pent-4-enoic acid ethyl ester 
• 28247-15-6 ethyl 1-acetylcyclopropane-1-carboxylate 
• 33626-80-1 ethyl 1-acetylcyclopent-3-ene-1-carboxylate 
• 99-14-9 tricarallylic acid 
• 99-67-2 2-allyl-4-pentenoic acid 
• 75265-80-4 3-allyl-hex-5-en-2-one 

Relevant articles and documents

Concerted Catalysis in Tight Spaces: Palladium-Catalyzed Allylation Reactions Accelerated by Accumulated Active Sites in Mesoporous Silica

The surface of mesoporous silica was modified with a Pd–bisphosphine complex and/or a tertiary amine group for concerted acceleration of allylation reactions. Mesoporous-silica-supported catalysts with a 1.6 nm pore diameter showed higher performance than nonporous or larger mesoporous silica-supported catalysts owing to the accumulation of active sites into a confined space. For the case in which allyl alcohol was used in the reaction, the presence of a silanol group on the surface was quite effective: the turnover number of Pd was nine times greater than that of the homogeneous Pd complex.

Heterogeneous synergistic catalysis by a palladium complex and an amine on a silica surface for acceleration of the Tsuji-Trost reaction

The cooperative surface-catalysis strategy of a Bronsted acid and an organic base can be extended to a metal complex and organic base pair. A silica-supported diaminopalladium complex and a tertiary amine were prepared and characterized. The Pd-catalyzed

Accumulation of Active Species in Silica Mesopore: Effect of the Pore Size and Free Base Additives on Pd-catalyzed Allylation using Allylic Alcohol

A mesoporous silica-supported Pd complex was prepared using various types of porous silica supports (pore size: 16–31 ?). The effects of the pore size and base additive properties on the catalytic allylation were investigated. The activity of the Pd-catal

Decarboxylative Annulation of α-Amino Acids with β-Ketoaldehydes

Indolizidine and quinolizidine derivatives are readily assembled from l-proline or (±)-pipecolic acid and β-ketoaldehydes via a decarboxylative annulation process. These reactions are promoted by acetic acid and involve azomethine ylides as reactive intermediates.

Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.