35412-25-0

Basic information

• Product Name: benzyl 6α-methoxy-6β-phenoxyacetamidopenicillanate
• Synonyms: benzyl 6α-methoxy-6β-phenoxyacetamidopenicillanate
• CAS NO: 35412-25-0
• Molecular Weight: 470.546
• Mol File: 35412-25-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: benzyl 6α-methoxy-6β-phenoxyacetamidopenicillanate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 6α-methoxy-6β-phenoxyacetamidopenicillanate(35412-25-0)
• EPA Substance Registry System: benzyl 6α-methoxy-6β-phenoxyacetamidopenicillanate(35412-25-0)

Safety Data

• Hazardous Substances Data: 35412-25-0(Hazardous Substances Data)

Upstream product

• 35353-31-2 benzyl 6β-azido-6-methoxypenicillanate 
• 39486-17-4 (5R)-6ξ-cyano-6ξ-hydroxy-3,3-dimethyl-7-oxo-(5rH)-4-thia-1-aza-bicyclo[3.2.0]heptane-2c-carboxylic acid benzyl ester 
• 1256-06-0 (2S,5R,6R)-benzyl-3,3-dimethyl-7-oxo-6-(2-phenoxyacetamido)-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylate 
• 55367-05-0 Benzyl 6α-(methylthio)-6β-(phenoxyacetamido)penicillanate 
• 85339-74-8 benzyl (2S,5R,6S)-6-methoxy-7-methoxycarbonyl-(E)-methylene-3,3-dimethyl-6-phenoxyacetamido-4-thia-1-azabicyclo<3.2.0>-heptane-2-carboxylate 
• 67-56-1 methanol 
• 104702-12-7 Benzyl 6α-(succinimido-oxy)-6β-(phenoxyacetamido)penicillanate 
• 97609-36-4 Benzyl 6α-Dimethylamino-6β-phenoxyacetamidopenicillanate 
• 53229-99-5 2-phenoxy-N-(triphenyl-λ⁵-phosphanylidene)-acetamide 
• 39126-59-5 6-oxopenicillanic acid benzyl ester 
• 80282-03-7 benzyl (2S,5R,6R)-(E)-7-methoxycarbonylmethylene-3,3-dimethyl-6-phenoxyacetamido-4-thia-1-azabicyclo<3.2.0>-heptane-2-carboxylate 
• 100-39-0 benzyl bromide 
• 85380-71-8 lithium (2S,5R,6R)-7-methoxycarbonyl-(E)-methylene-3,3-dimethyl-6-phenoxyacetamido-4-thia-1-azabicyclo<3.2.0>-heptane-2-carboxylate 

Downstream Products

• 35353-34-5 6α-methoxy-6β-(2-phenoxy-acetylamino)-penicillanic acid 

Relevant articles and documents

Further Synthetic Studies in Penicillin C(6)-Substitution Including the Versatile 6&α-Succinimidooxy Leaving Group

Treatment of benzyl 6α-dimethylamino-6β-phenoxyacetamidopenicillanate 3 with methyl iodide led, in the absence of added nucleophiles, to the oxygen-bridged dimer 8 via adventitious water present.Added methanol or water led to the 6α-methoxy or -hydroxy pr

Penicillin C-6 Substitution using the Versatile 6α-Succinimido-oxy Leaving Group

Reaction of benzyl 6α-(methylthio)-6β-(phenoxyacetamido)penicillanate with N-hydroxysuccinimide catalysed by silver(I) acetate afforded the stable 6α-(succinimido-oxy) derivative; this species on reaction with various nucleophiles gave a range of 6α-subst

1-Aza-[3.2.0]-bicycloheptane-2-carboxylic acid, ester or salt thereof

A 1-aza[3.2.0]bicycloheptan-2-carboxylic acid or salt or ester thereof having a substituent at position 7 of the formula: wherein R1 and R2 are independently hydrogen, halogen or an organic group.