355-25-9Relevant articles and documents
Reed
, p. 221,225 (1958)
Synthesis of perfluoroalkanes in high-temperature fluorination of graphite with fluorine in a reactor with a free-falling graphite bed
Shelopin,Pashkevich,Alekseev,Mukhortov,Petrov,Asovich
, p. 1031 - 1034 (2006)
Reaction between fluorine and graphite in a reactor with a free-falling bed of graphite was studied in relation to the temperature in the reaction zone, ratio of the feeding rates of fluorine and graphite, and dilution of fluorine with an inert gas. Pleiades Publishing, Inc., 2006.
Dresdner
, p. 69 (1957)
Baba et al.
, p. 2809 (1977)
Synthesis of perfluoroalkanes by high-temperature reaction of graphite with fluorine in a fluidized bed
Pashkevich,Shelopin,Mukhortov,Petrov,Alekseev,Asovich
, p. 1847 - 1853 (2004)
Synthesis of lower perfluoroalkanes (tetrafluoromethane, hexafluoroethane, octafluoropropane, decafluorobutane) by high-temperature reaction of graphite with fluorine in a fluidized bed was studied.
Decomposition characteristics of C5F10O/air mixture as substitutes for SF6 to reduce global warming
Li, Yi,Zhang, Xiaoxing,Xiao, Song,Chen, Qi,Wang, Dibo
, p. 65 - 72 (2018/02/14)
Sulfur hexafluoride (SF6) is widely used in the power industry but is a serious greenhouse gas. Many researchers committed to achieving sustainable development of the power industry are finding alternatives to SF6 gas. C5F10O performs well in terms of environmental protection, insulation, and safety and is a potential environment-friendly alternative gas. In this paper, the insulation and decomposition characteristics of C5F10O/air gas mixture were examined using gas-insulation performance test platform, and decomposition products were detected by gas chromatography–mass spectrometry. The formation mechanism and distribution of C5F10O decomposition products were analyzed through reactive molecular dynamics method and density functional theory. The influence of air on the decomposition of C5F10O was also evaluated. Results showed that the decomposition of C5F10O/air gas mixture mainly produces CF3[rad], C3F7[rad], C4F7O[rad], CO, CF2[rad], CF[rad], F[rad] and CF4. The breakdown voltage of C5F10O/air gas mixture decreased slightly after repeated breakdown tests, and CF4, C2F6, C3F8, C3F6, C4F10, CF2O were detected. These results can serve as a reference for the systematic comprehension of the decomposition characteristics of C5F10O/air gas mixture and for related engineering applications.
Investigation of CF2 carbene on the surface of activated charcoal in the synthesis of trifluoroiodomethane via vapor-phase catalytic reaction
Yang, Guang-Cheng,Lei, Shi,Pan, Ren-Ming,Quan, Heng-Dao
experimental part, p. 231 - 235 (2009/08/07)
This paper investigates the synthetic mechanism of trifluoroiodomethane (CF3I) in the reaction of trifluoromethane and iodine via vapor-phase catalytic reaction. It is suggested that CF2 carbene is the key intermediate and is formed in the pyrolysis process of CHF3 at high temperature. However, in pyrolysis of CHF3 under activated charcoal (AC) existing conditions, no C2F4 was detected. H2 and 2-methyl-2-butene could not trap the CF2 carbene. When treating the remained compounds on the used AC with H2, CH4 is formed on the process. It is proposed that CF2 carbene combines with AC strongly and transfers into CF3 radical on heat. In addition, it is found that the AC is not only the catalyst supporter to form CF3I, but also a co-catalyst to promote the formation of CF2 carbene and CF3 radical.