36050-78-9Relevant academic research and scientific papers
Phenylsilyl Chalcogenides, (Phenylsilyl)amines and Related Phosphonium (Phenylsilyl)methylides
Mitzel, Norbert W.,Schier, Annette,Beruda, Holger,Schmidbaur, Hubert
, p. 1053 - 1060 (2007/10/02)
The synthesis of 1,3-diphenyldisiloxane (1) by hydrolysis of chloro(phenyl)silane is optimized, 1,3-diphenyldisilthiane (2) is made available by the reaction of H2S with PhH2SiCl and triethylamine. 1,3-Diphenyldisilselenane (3) is prepared from K2Se and P
Synthesis and reactions of [1-(trialkylsilyl)alkylidene]triphenylphosphoranes
Bestmann,Bomhard,Dostalek,Pichl,Riemer,Zimmermann
, p. 787 - 792 (2007/10/02)
Alkylidenetriphenylphosphoranes 1 react with trialkyl halosilanes 2 to afford silylated alkylidenephosphoranes 5, which can be converted to acylated alkylidenephosphoranes 8 and 10 by trimethylsilyl carboxylates 6 or carboxylic anhydrides 10. Bis(acylalkylidenephosphoranes) 13-15 are available from 5 and bis(trimethylsilyl) dicarboxylates 12 or cyclic or polymeric anhydrides 16, 17.
