362470-30-2

Basic information

• Product Name: (+/-)-3-benzyloxy-4,4-dimethylpyrrolidin-2-one
• Synonyms: (+/-)-3-benzyloxy-4,4-dimethylpyrrolidin-2-one
• CAS NO: 362470-30-2
• Molecular Weight: 219.283
• Mol File: 362470-30-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-3-benzyloxy-4,4-dimethylpyrrolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-3-benzyloxy-4,4-dimethylpyrrolidin-2-one(362470-30-2)
• EPA Substance Registry System: (+/-)-3-benzyloxy-4,4-dimethylpyrrolidin-2-one(362470-30-2)

Safety Data

• Hazardous Substances Data: 362470-30-2(Hazardous Substances Data)

Upstream product

• 117895-47-3 3-(benzyloxy)-4,4-dimethyldihydrofuran-2(3H)-one 
• 100-39-0 benzyl bromide 

Downstream Products

• 362470-63-1 (S)-2-(3-Benzoyl-phenyl)-propionic acid (S)-1-carbamoylmethyl-4,4-dimethyl-2-oxo-pyrrolidin-3-yl ester 
• 362470-66-4 (S)-1-carbamoylmethyl-4,4-dimethyl-2-oxopyrrolidinyl (S)-2-(4-isobutylphenyl)propionate 
• 737762-31-1 [1-(2-methoxyethyl)-4,4-dimethyl-2-oxopyrrolidin-3-yl] 4-methylcyclohex-3-ene-1-carboxylate 
• 737762-26-4 (+/-)-3-benzyloxy-1-(2-methoxyethyl)-4,4-dimethylpyrrolidin-2-one 
• 737762-24-2 (+/-)-ethyl 6-(3-benzyloxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)hexanoate 
• 362470-32-4 (RS)-(3-benzyloxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)acetic acid tert-butyl ester 

Relevant articles and documents

Toward Diels-Alder reactions on a solid support using polymer bound N-substituted 3-hydroxy-4,4-dimethyl-2-pyrrolidinone acrylate derivatives

Several N-substituted 3-hydroxy-4,4-dimethyl-2-pyrrolidinone acrylate derivatives, selected to allow their attachment to a polymer, have been prepared and tested as dienophiles in the Diels-Alder reaction. The experiments, performed under TiCl4 catalysis in solution or the solid phase with isoprene and cyclopentadiene as dienes, pointed out the difficulties associated with some of these compounds that failed to give the corresponding cycloadduct. 13C NMR studies provided some evidence regarding the nature of the interactions between the acrylate compounds and TiCl4. It appears that the outcome of the reaction is dependent on the acrylate structure and that the 4-(3-hydroxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)benzoic acid acrylate derivatives are highly efficient to give the cycloadduct in good yield and with high regio- or endoselectivity in both solution and solid-phase reaction conditions. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.