36309-42-9

Basic information

• Product Name: Benzenamine, 4-[(trimethylsilyl)oxy]-
• CAS NO: 36309-42-9
• Molecular Formula: C9H15NOSi
• Molecular Weight: 181.31
• Mol File: 36309-42-9.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-[(trimethylsilyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-[(trimethylsilyl)oxy]-(36309-42-9)
• EPA Substance Registry System: Benzenamine, 4-[(trimethylsilyl)oxy]-(36309-42-9)

Safety Data

• Hazardous Substances Data: 36309-42-9(Hazardous Substances Data)

Upstream product

• 123-30-8 4-amino-phenol 
• 754-05-2 ethenyltrimethylsilane 
• 75-77-4 chloro-trimethyl-silane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 108908-65-2 [(E)-2-Methyl-3-phenyl-prop-2-en-(Z)-ylidene]-(4-trimethylsilanyloxy-phenyl)-amine 
• 42003-65-6 4-<(trimethylsilyl)oxy>phenyl isocyanate 
• 123-30-8 4-amino-phenol 
• 313706-05-7 (CH₃)3SiOC₆H₄NTiCl₂(C₅H₅N)3 
• 956111-26-5 1,10-phenanthroline-2-carboxamide-phenyl-4-ethoxypiperidine palladium(II) chloride 
• 956111-27-6 1,10-phenanthroline-2-carboxamide-phenyl-4-ethoxypiperidine platinum(II) chloride 
• 956111-36-7 1,10-phenanthroline-2-carboxamide-phenyl-4-ethoxypiperidine 
• 313706-04-6 [C₅H₅TiClNC₆H₄OSi(CH₃)3]2 
• 956111-34-5 4-hydroxyphenyl-1,10-phenanthroline-2-carboxamide 
• 1266331-36-5 N,N'-bis(4-aminophenol)-1,10-phenanthroline-2,9-carboxamide 
• 1301127-07-0 N,N'-bis(phenyl-4-ethoxydimethylamino)-1,10-phenanthroline-2,9-carboxamide 
• 1301127-06-9 N,N'-bis(phenyl-4-ethoxymorpholine)-1,10-phenanthroline-2,9-carboxamide 
• 1266331-38-7 N,N'-bis(phenyl-4-ethoxypyrrole)-1,10-phenanthroline-2,9-carboxamide 
• 1266331-37-6 N,N'-bis(phenyl-4-ethoxypiperidine)-1,10-phenanthroline-2,9-carboxamide 

Relevant articles and documents

Activation of hexamethyldisilazane (HMDS) by TiO2 nanoparticles for protection of alcohols and phenols: the effect of the catalyst phase on catalytic activity

Anatase TiO2 nanoparticles (TiO2 NPs) were synthesized by the sol–gel method using titanium tetra-isopropoxide (TTIP), isopropyl alcohol, and distilled water and then calcined at 400?°C for 3?h. X-ray diffraction and scanning electron microscopy methods, and Fourier transform infrared spectroscopy were used for characterization of the obtained TiO2 NPs. The obtained anatase TiO2 NPs were used as heterogeneous catalyst for trimethylsilation of various alcohols or phenols with hexamethyldisilazane (HMDS) in CH3CN at room temperature. High to quantitative yields of the products were obtained within short reaction times at room temperature using a very low loading of pure TiO2 NPs without any post-modification with Bronsted or Lewis acid species such as ClSO3H or HClO4. The catalyst can be recycled at least three times without significant loss of its activity. The results of this study provide evidence that the pure anatase phase of TiO2 exhibits higher catalytic activity in terms of catalyst loading and required reaction time compared to a mixture of anatase and rutile phases found in the commercial samples for trimethylsilation of various alcohols or phenols with HMDS.

Nano Fe3O4@ZrO2/SO42?: A highly efficient catalyst for the protection and deprotection of hydroxyl groups using HMDS under solvent-free condition

In this work, we introduce a new procedure for the protection and deprotection process of various types of alcohols and phenols by HMDS in the presence of nano magnetic sulfated zirconia (Fe3O4@ZrO2/SO42?) as a solid acid catalyst under very mild and solvent-free condition. This method has interesting advantages like short reaction times and a simple workup process. With regard to some outstanding benefits of this new heterogeneous catalyst such as excellent yield, reusability of the catalyst and easy thermal stability, high acidity, strong and excellent magnetic properties, this method can be very interesting in aspect of green chemistry Principles.

Preparation of nano silica supported sodium hydrogen sulfate: As an efficient catalyst for the trimethyl, triethyl and t-butyldimethyl silylations of aliphatic and aromatic alcohols in solution and under solvent-free conditions

Nano silica supported sodium hydrogen sulfate has been prepared by mixing NaHSO4 with activated Nano silicagel. We wish to report a new method for the synthesis of trimethyl (TMS), triethyl (TES) and t-butyldimethyl silyl (TBS) ethers from benzylic, allylic, propargylic alcohols, phenols, naphtholes and some of phenolic drugs in the solution and under solvent-free conditions.