3661-49-2

Basic information

• Product Name: Benzenamine, 3-methoxy-N-(4-methoxyphenyl)-
• CAS NO: 3661-49-2
• Molecular Formula: C14H15NO2
• Molecular Weight: 229.279
• Mol File: 3661-49-2.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzenamine, 3-methoxy-N-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 3-methoxy-N-(4-methoxyphenyl)-(3661-49-2)
• EPA Substance Registry System: Benzenamine, 3-methoxy-N-(4-methoxyphenyl)-(3661-49-2)

Safety Data

• Hazardous Substances Data: 3661-49-2(Hazardous Substances Data)

Upstream product

• 2398-37-0 3-methoxyphenyl bromide 
• 104-94-9 4-methoxy-aniline 
• 2845-89-8 1-chloro-3-methoxy-benzene 
• 536-90-3 m-Anisidine 
• 115298-63-0 phenyl(4-methoxyphenyl)iodonium triflate 
• 696-62-8 para-iodoanisole 
• 27126-77-8 (4-methoxyphenyl)phenyliodonium p-toluenesulfonate 
• 555-03-3 3-nitroanisole 
• 5720-07-0 4-methoxyphenylboronic acid 
• 100-17-4 para-methoxynitrobenzene 
• 100-66-3 methoxybenzene 
• 766-85-8 3-methoxy-1-iodobenzene 
• 540-38-5 p-Iodophenol 
• 104-92-7 1-bromo-4-methoxy-benzene 

Downstream Products

• 944284-88-2 [(3-methoxyphenyl)-4-methoxyphenylamino]acetonitrile 
• 1573202-44-4 N²,N²,N^2',N^2',N⁷,N⁷,N^7',N^7'-octakis(3-methoxypheny)-9,9'-spirobi[fluorene]-2,2',7,7'-tetraamine 
• 109688-74-6 2-methoxy-N⁴-(4-methoxy-phenyl)-p-phenylenediamine 

Relevant articles and documents

Cu-Catalyzed Cross-Coupling of Nitroarenes with Aryl Boronic Acids to Construct Diarylamines

The development and study of a simple copper-catalyzed reaction of nitroarenes with aryl boronic acids to form diarylamines that uses phenyl silane as the stoichiometric terminal reductant is described. This cross-coupling reaction requires as little as 2 mol % of CuX and 4 mol % of diphosphine for success and tolerates a broad range of functional groups on either the nitroarene or the aryl boronic acid to afford the amine in good yield. Mechanistic investigations established that the cross-coupling reaction proceeds via a nitrosoarene intermediate and that copper is required to catalyze both the deoxygenation of the nitroarene to afford the nitrosoarene and C-NAr bond formation of the nitrosoarene with the aryl boronic acid.

A terphenyl phosphine as a highly efficient ligand for palladium-catalysed amination of aryl halides with 1° anilines

A terphenyl phosphine ligand (2,6-bis(2,4,6-triisopropylphenyl)phenyl-dicyclohexylphosphine, TXPhos) and its supported palladium complex [(TXPhos)(allyl)PdCl] have been developed and the catalyst system is highly efficient in amination of aryl halides with 1° anilines, especially effective for densely functionalized substrates including both partners possessing ortho-ester, acetyl, nitrile and nitro groups. With the TXPhos-supported catalyst system, many partner combinations have been unprecedentedly realized and the base scope has been even extended to KOAc, which is even the best choice in the amination of 2-nitrochlorobenzene.

Hole transporting material taking carbazoles bonded with tetracarbon chain as core as well as preparation method and application of hole transporting material

The invention discloses a novel hole transporting material taking carbazoles bonded with a tetracarbon chain as a core as well as a preparation method and application of the novel hole transporting material. The hole transporting material taking carbazole