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36629-42-2

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36629-42-2 Usage

Chemical Properties

clear colorless to light yellow liquid

Uses

Methyl pentafluorobenzoate was used in preparation of photocoupling agent, based on perfluorophenylazide (PFPA)-conjugated polyallylamine, for efficient immobilization of polymers, nanoparticles, graphene and small molecules. It was also used in preparation of photoactive reagent N-hydroxysuccinimide (NHS)-PFPA.

Check Digit Verification of cas no

The CAS Registry Mumber 36629-42-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,6,2 and 9 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 36629-42:
(7*3)+(6*6)+(5*6)+(4*2)+(3*9)+(2*4)+(1*2)=132
132 % 10 = 2
So 36629-42-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H3F5O2/c1-15-8(14)2-3(9)5(11)7(13)6(12)4(2)10/h1H3

36629-42-2Relevant articles and documents

Study of Pd-elimination under carbonylation conditions: Regioselective formation of esters

Albeniz, Ana C.,Espinet, Pablo,Lin, Yong-Shou

, p. 13851 - 13866 (1998)

The regioselective synthesis of methyl esters is achieved by carbonylation of two different types of organometallic derivatives resulting from insertion of non-conjugated dienes into a Pd-aryl bond. When the diene and the Pd-aryl synthon [PdPfBr(NCMe)2] (Pf = C6F5) are mixed at low temperature, solutions of η1-η2-enylpalladium complexes can be isolated and converted into β-aryl methyl esters by reaction with CO in the presence of methanolic solutions of sodium methoxide. When the reactions are carried out at room temperature η3-allylpalladium complexes are isolated, and their carbonylation gives β,γ-unsaturated esters.

SOLID FORMS OF AN FGFR INHIBITOR AND PROCESSES FOR PREPARING THE SAME

-

Page/Page column 92-93, (2019/11/19)

The present disclosure relates to 3-(2,6-difluoro-3,5-dimethoxyphenyl)-1-ethyl-8-(morpholin-4-ylmethyl)-1,3,4,7-tetrahydro-2H-pyrrolo[3',2':5,6]pyrido[4,3-d]pyrimidin-2-one, solid forms and polymorphs thereof, methods of preparation thereof, and intermediates in the preparation thereof, which are useful in the treatment of the FGFR-associated or mediated diseases such as cancer.

Photocatalytic hydrodefluorination: Facile access to partially fluorinated aromatics

Senaweera, Sameera M.,Singh, Anuradha,Weaver, Jimmie D.

supporting information, p. 3002 - 3005 (2014/03/21)

Polyfluorinated aromatics are essential to materials science as well as the pharmaceutical and agrochemical industries and yet are often difficult to access. This Communication describes a photocatalytic hydrodefluorination approach which begins with easily accessible perfluoroarenes and selectively reduces the C-F bonds. The method allows facile access to a number of partially fluorinated arenes and takes place with unprecedented catalytic activity using a safe and inexpensive amine as the reductant.

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