36640-14-9

Usage

InChI:InChI=1/C17H18O4/c1-20-14-10-7-12(8-11-14)6-9-13-4-3-5-15(21-2)16(13)17(18)19/h3-5,7-8,10-11H,6,9H2,1-2H3,(H,18,19)

Upstream product

• 113345-85-0 3,4'-dimethylstilbene-2-carboxylic acid 
• 118842-86-7 3,4'-Dimethoxybibenzyl-2-carbonsaeureethylester 
• 6161-65-5 2-methoxy-6-methyl-benzoic acid 
• 824-94-2 p-methoxybenzyl chloride 
• 118842-83-4 (2-Ethoxycarbonyl-3-methoxybenzyl)triphenylphosphoniumbromid 
• 21615-34-9 2-Methoxybenzoyl chloride 
• 125023-40-7 N-tert-Butyl-N-methyl-2-methoxy-6-<2-(4-methoxyphenyl)ethyl>benzamide 
• 125023-41-8 N-Methyl-2-methoxy-6-<2-(4-methoxyphenyl)ethyl>benzamide 
• 95330-45-3 N-tert-Butyl-N-methyl-2-methoxy-6-methylbenzamide 
• 95330-46-4 N-tert-Butyl-N-methyl-2-methoxybenzamide 
• 86823-81-6 6-bromomethyl-2-methoxy-benzoic acid ethyl ester 
• 6520-83-8 ethyl 2-methoxy-6-methylbenzoate 
• 3462-97-3 (4-methoxybenzyl)triphenylphosphonium bromide 
• 53015-08-0 2-formyl-6-methoxy-benzoic acid 

Downstream Products

• 23255-59-6 lunularic acid 
• 118842-94-7 3,4'-Dimethoxybibenzyl-2-carbonsaeurechlorid 
• 118842-98-1 Lunularsaeureamid 
• 118842-95-8 3,4'-Dimethoxybibenzyl-2-carbonsaeureamid 
• 118842-99-2 Lunularsaeurediethylamid 
• 118842-96-9 N,N-Diethyl-2-methoxy-6-[2-(4-methoxy-phenyl)-ethyl]-benzamide 
• 118843-00-8 Lunularsaeuremorpholid 
• 118842-97-0 3,4'-Dimethoxybibenzyl-2-carbonsaeuremorpholid 

Relevant academic research and scientific papers

Directed ortho-metalation of unprotected benzoic acids. Methodology and regioselective synthesis of useful contiguously 3- and 6-substituted 2-methoxybenzoic acid building blocks

By treatment with s-BuLi/TMEDA at -78 °C, unprotected 2-methoxybenzoic acid is deprotonated exclusively in the position ortho to the carboxylate. A reversal of regioselectivity is observed when the acid is treated with n-BuLi/t-BuOK. These results are of general utility for the one-pot preparation of a variety of very simple 3- and 6-substituted 2-methoxybenzoic acids that are not easily accessible by conventional means. The potential usefulness of the method is demonstrated by the expedient synthesis of lunularic acid.

Inhibiting effects of lunularic acid analogs on the growth of liverwort, watercress, and timothy grass

A number of analogs of lunularic acid varying in the number of methylene carbons between the two benzene rings and in the substituents on their rings were prepared, and their effects on the growth of liverwort gemmaling, watercress, and timothy grass were

Regioselectivity in the Reductive Cleavage of Pyrogallol Derivatives: Reductive Electrophilic Substitution of Acetals of 2,3-Dimethoxyphenol

Acetals of 2,3-dimethoxyphenol were used as the starting materials for the transformation of 1,2,3-trioxygenated benzenes into various 1-oxygenated-2,3-dicarbon-substituted benzenes, via regioselective reductive electrophilic substitution of the 2-methoxy

Convenient syntheses of 3-aryl-3,4-dihydroisocoumarins and lunularic acid derivatives

A convenient two-step approach for the syntheses of 3-aryl-3,4-dihydroisocoumarins (13-17) including some naturally occurring 3-aryl-8-hydroxy-3,4-dihydroisocoumarins (1,2) and lunularic acid derivatives (18-21) is described from 2-formylbenzoic acids (4,