36873-45-7 Usage
Synthesis Reference(s)
Journal of the American Chemical Society, 72, p. 803, 1950 DOI: 10.1021/ja01158a040
Check Digit Verification of cas no
The CAS Registry Mumber 36873-45-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,8,7 and 3 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 36873-45:
(7*3)+(6*6)+(5*8)+(4*7)+(3*3)+(2*4)+(1*5)=147
147 % 10 = 7
So 36873-45-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H12O3/c1-3-5-7(6-9)8(10)11-4-2/h3,6-7H,1,4-5H2,2H3
36873-45-7Relevant articles and documents
A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis
Chung, William,Lindovska, Petra,Camp, Jason E.
supporting information; experimental part, p. 6785 - 6787 (2012/01/03)
A step-economical one-pot nucleophilic catalysis/thermal Claisen-rearrangement protocol for the direct synthesis of α-formyl- α-allylacetates from allylic alcohols and activated alkynes has been developed. The product α-formyl-α-allylacetates were further reacted in situ to give either protected enol ethers or β-hydroxy-4-pentenoates.
