5941-55-9

Basic information

• Product Name: ETHYL TRANS-3-ETHOXYACRYLATE, 98
• Synonyms: ETHYL TRANS-3-ETHOXYACRYLATE, 98;TRANS-ETHYL 3-ETHOXYACRYLATE;trans-Ethyl 3-ethoxyacrylate
• CAS NO: 5941-55-9
• Molecular Formula: C₇H₁₂O₃
• Molecular Weight: 144.1684
• Mol File: 5941-55-9.mol
• Article Data: 8

Chemical Properties

• Melting Point: -34°C
• Boiling Point: 196°C
• Flash Point: 76°C
• Appearance: /
• Density: 1 g/cm3
• Vapor Pressure: 0.418mmHg at 25°C
• Refractive Index: 1.4460
• Storage Temp.: 2-8°C
• Water Solubility: soluble
• BRN: 1721612
• CAS DataBase Reference: ETHYL TRANS-3-ETHOXYACRYLATE, 98(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL TRANS-3-ETHOXYACRYLATE, 98(5941-55-9)
• EPA Substance Registry System: ETHYL TRANS-3-ETHOXYACRYLATE, 98(5941-55-9)

Safety Data

• Hazard Codes: Xi:Irritant
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 5941-55-9(Hazardous Substances Data)

Usage

Chemical Properties

Colorless transparent liquid

InChI:InChI=1/C7H12O3/c1-3-9-6-5-7(8)10-4-2/h5-6H,3-4H2,1-2H3/b6-5+

Upstream product

• 623-47-2 propynoic acid ethyl ester 
• 64-17-5 ethanol 
• 10601-80-6 ethyl 3,3-diethoxypropanoate 
• 6191-99-7 (2E)-3-ethoxyprop-2-enoyl chloride 
• 141-78-6 ethyl acetate 
• 109-94-4 formic acid ethyl ester 
• 69194-04-3 (Z)-3-methoxypropenenitrile 
• 69194-03-2 3-methoxy-2-propenenitrile 

Downstream Products

• 855641-73-5 5-formyl-4-hydroxy-isophthalic acid diethyl ester 
• 75717-35-0 ethyl (E)-3-(phenylthio)-2-propenoate 
• 4105-92-4 triethyl benzene-1,3,5-tricarboxylate 
• 7504-67-8 4-hydroxy-5-methyl-isophthalic acid diethyl ester 
• 773138-32-2 2-hydroxy-benzene-1,3,5-tricarboxylic acid triethyl ester 
• 85997-26-8 ethyl (E)-3-(benzyloxy)propenoate 
• 86197-67-3 benzyl (E)-benzyloxyacrylate 
• 872973-88-1 1-(2,6-dichlorophenyl)-6-(4-methoxybenzyl)-1,6-naphthyridone-2,5,7-(1H,6H,8H)-trione 
• 892874-83-8 diethyl 6-methoxyquinoline-2,3-dicarboxylate 
• 1326224-17-2 triethyl 1,4-dihydro-1-(4-methoxyphenyl)pyridine-3,4,5-tricarboxylate 
• 1226762-74-8 7-bromoquinoline-3-carboxylic acid ethyl ester 
• 926663-00-5 5-hydroxypyrazole[1,5-a]pyrimidine-3-carboxylic acid ethyl ester 
• 6191-99-7 3-ethoxyacryloyl chloride 
• 36873-45-7 ethyl 2-formylpent-4-enoate 

Relevant articles and documents

Platinum- and gold-catalyzed hydroalkoxylation and tetramerization of propiolate esters

PtCl2 was found to efficiently catalyze intermolecular additions of propiolate esters with alcohols. The reaction of propiolate esters and alcohols in the presence of PtCl2 gave (E)-vinyl ethers as the major products at 60 °C, whereas alkyl 3,3-dialkoxypropanoates were predominantly obtained when the reaction temperature was set to 80°C. On the other hand, a novel regioselective tetramerization of propiolate esters catalyzed by AuCl3 under mild conditions afforded 1,2,5,6-tetrasubstituted- cyclooctatetraene (1,2,5,6-COT) in moderate yields.

METHOD FOR PRODUCING SUBSTITUTED VINYL ETHER DERIVATIVE

PROBLEM TO BE SOLVED: To provide a method for producing a substituted vinyl ether derivative by ether exchange from a substituted vinyl ether which has an electron-attracting group as a substituent on a double bond carbon atom to cause the binding site to be electron-deficient. SOLUTION: The method for producing a substituted vinyl ether derivative comprises subjecting a substituted vinyl ether, which has at least one electron-attracting group as a substituent on a carbon atom which forms carbon-carbon double bond, to ether exchange reaction with an alcohol or a phenol in the presence of a catalyst containing a compound of the group 9 and/or 10 metal in the periodic table, wherein the compound has a counter anion, and when the anion is protonated, the proton has an ionization constant (pKa) of 0 or less.