Ethyl 2-formylpent-4-en-1-oate

Base Information

Chemical Name:Ethyl 2-formylpent-4-en-1-oate
CAS No.:36873-45-7
Molecular Formula:C8H12 O3
Molecular Weight:156.181
Hs Code.:2918300090
European Community (EC) Number:253-246-8
DSSTox Substance ID:DTXSID60958073
Nikkaji Number:J260.691G
Mol file:36873-45-7.mol

Synonyms:Ethyl 2-formylpent-4-en-1-oate;ethyl 2-formylpent-4-enoate;36873-45-7;EINECS 253-246-8;DTXSID60958073;2-Formyl-4-pentenoic acid ethyl ester

Suppliers and Price of Ethyl 2-formylpent-4-en-1-oate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Ethyl 2-formylpent-4-en-1-oate

Chemical Property:

Vapor Pressure:0.524mmHg at 25°C
Boiling Point:191.1°Cat760mmHg
Flash Point:71.1°C
PSA：43.37000
Density:0.995g/cm³
LogP:0.94070
XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:156.078644241
Heavy Atom Count:11
Complexity:151

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(CC=C)C=O

Technology Process of Ethyl 2-formylpent-4-en-1-oate

There total 7 articles about Ethyl 2-formylpent-4-en-1-oate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 74649-09-5
(E)-3-(2-Propenyloxy)propensaeure-ethylester

: 36873-45-7
ethyl 2-formylpent-4-enoate

Guidance literature:: With β-naphthol; at 155 ℃;
DOI:10.1021/ja01158a040

Reference yield:

: 5941-55-9
ethyl 3-ethoxyacrylate

: 36873-45-7
ethyl 2-formylpent-4-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydrogen sulfate / 125 °C

2: <2>naphthol / 155 °C

With sodium hydrogen sulfate; β-naphthol;
DOI:10.1021/ja01158a040

Reference yield:

: 623-47-2
propynoic acid ethyl ester

: 36873-45-7
ethyl 2-formylpent-4-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1,4-diaza-bicyclo[2.2.2]octane / dichloromethane / 0.67 h / 20 °C

2: toluene / 15 h / 150 °C

With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; toluene; 2: Claisen rearrangement;
DOI:10.1016/j.tetlet.2011.10.035