3708-06-3Relevant academic research and scientific papers
Synthesis of arylethyl (E)-styrylsulfones and arylsulfones by one-pot DIBAL-H/NaH-mediated reaction of β-ketosulfones
Chang, Meng-Yang,Chen, Yi-Chia,Chan, Chieh-Kai
, p. 1739 - 1744 (2014/08/05)
A facile one-pot synthetic route for preparing a series of arylethyl (E)-styrylsulfones or arylethyl arylsulfones is developed. The efficient one-pot DIBAL-H/NaH-mediated route includes reduction of α-benzyl-β- arylketosulfones and retroaldol/aldol or retro aldol reaction of the resulting intermediate. The DIBAL-H/NaH-mediated reaction mechanism has been discussed. Georg Thieme Verlag Stuttgart. New York.
TANDEM REDUCTION-DESULFONYLATION OF α-ALKYLIDENE-β-KETO SULFONES
Huang, Xian,Zhang, Han-zhong
, p. 97 - 106 (2007/10/02)
α-Alkylidene-β-keto sulfones take place both reduction of carbon-carbon double bond and desulfonylation with the use of sodium hydrogen telluride in ethanol-N,N-dimethylformamide.
