3709-35-1Relevant academic research and scientific papers
New dimerization and cascade oligomerization reactions of dimethyl 2-phenylcyclopropan-1,1-dicarboxylate catalyzed by Lewis acids
Novikov, Roman A.,Korolev, Victor A.,Timofeev, Vladimir P.,Tomilov, Yury V.
scheme or table, p. 4996 - 4999 (2011/10/08)
New routes to transform donor-acceptor cyclopropanes in the presence of Lewis acids have been found. The reaction of dimethyl 2-phenylcyclopropan-1,1- dicarboxylate, a typical representative of this class of compounds, with an equimolar amount of anhydrou
Oxidative addition of dimethyl malonate to styrenes mediated by cerium(IV) ammonium nitrate: Some novel observations
Nair, Vijay,Mathew, Jessy,Nair, Latha G.
, p. 3053 - 3064 (2007/10/03)
The oxidative addition of dimethyl malonate to ring substituted styrenes leads to the formation of substituted dimethyl (2-oxo-2-phenylethyl) malonate and methyl 2-oxo-5-phenyltetrahydrofuran-3-carboxylate along with small amounts of substituted dimethyl [2-(nitrooxy)-2-phenylethyl] malonate and dimethyl 2-methoxy-2-phenylethyl) malonate. A tentative mechanism which supports the formation of these products is also presented.
Cerium(IV) ammonium nitrate mediated addition of dimethyl malonate to styrene: a remarkable reaction
Nair, Vijar,Jessy, Methew
, p. 1881 - 1882 (2007/10/02)
Cerium(IV) ammonium nitrate mediated addition of dimethyl malonate to styrene afforded the products 3 and 4 (via 7) along with small amounts of 5 and 6.
Relative Rates for the Addition Reactions of the Malonyl Radical to Substituted Styrenes Induced by Cerium(IV) Ammonium Nitrate and Tributyltin Hydride. A Comparison
Baciocchi, Enrico,Giese, Bernd,Farshchi, Hassan,Ruzziconi, Renzo
, p. 5688 - 5691 (2007/10/02)
The relative rates for the addition reactions of the malonyl radical to substituted styrenes induced by cerium(IV) ammonium nitrate (CAN) and tributyltin hydride have been determined.The two processes exhibit practically identical ρ+ values (-1.05 and -1.06), thus suggesting that the coordination between the metal and the radical does not play a significant role in the CAN-promoted oxidative additions.
