371978-06-2

Upstream product

• 67-64-1 acetone 
• 371978-05-1 (1R,2R,3E)-1-phenyl-pent-3-en-1,2,5-triol 
• 39806-16-1 ethyl (2E,4E)-5-phenyl-penta-2,4-dienoate 
• 211614-43-6 methyl (R)-(methoxymethoxy)(phenyl)ethanoate 
• 211614-44-7 (1R,2R)-5-(tert-butyldiphenylsilyloxy)-1-methoxymethoxy-1-phenyl-pent-3-yn-2-ol 
• 211614-45-8 (1R,2R,3E)-5-(tert-butyldiphenylsilyloxy)-1-methoxymethoxy-1-phenyl-pent-3-ene-2-ol 
• 161807-50-7 (2E,4R,5R)-4,5-dihydroxy-5-phenylpent-2-enoic acidethylester 
• 326603-41-2 ethyl (E)-3-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]prop-2-enoate 

Downstream Products

• 371978-11-9 (3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pentanenitrile 
• 371978-12-0 (3S,4S,5R,6R)-3-tert-butyldimethylsilyloxy-5,6-di-O-isopropylidenedioxy-4-methyl-6-phenyl-hexanal 
• 371978-10-8 (3S,4S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-3-hydroxy-pentanenitrile 
• 371978-08-4 (1R,2R,3S,4R)-1,2-di-O-isopropylidene-3-methyl-1-phenyl-pentan-1,2,4,5-tetrol 
• 371978-09-5 (1R,2R,3S,4R)-1,2-di-O-isopropylidene-4,5-epoxy-3-methyl-1-phenyl-pentan-1,2-diol 
• 934666-67-8 (1R)-1-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]propane-1,3-diol 
• 934666-69-0 methyl (Z,5R)-5-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]-5-hydroxypent-2-enoate 
• 934666-68-9 (3R)-3-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]-3-hydroxypropanal 

Relevant academic research and scientific papers

A simple and efficient total synthesis of a styryllactone, 7-epi-goniodiol

Regioselective mono-dihydroxylation, Red-Al reduction, and cis-Horner-Wadsworth-Emmons reactions have been efficiently performed as key steps in the synthesis of 7-epi-goniodiol, isolated from Goniothalamus leiocarpus. Georg Thieme Verlag Stuttgart.

Diastereocontrolled synthesis of unit A of cryptophycin

Cryptophycin fragment A was prepared in 11 steps from protected methyl (R)-mandelate 4. A diastereoselective addition of magnesium acetylide to methyl mandelate and a Sharpless epoxidation followed by regioselective opening of the resulting epoxide allowe